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Advances in Organometallic Chemistry Research

Editat de Kenji Yamamoto
en Limba Engleză Hardback – 5 iun 2007
This new and important book presents recent advances in organometallic chemistry which is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. Research in organometallic chemistry is also conducted in the areas of cluster synthesis, main-group derivatives in unusual oxidation states, organometallic polymers, unstable organometallic compounds and intermediates in matrices, structure determination of organometallic compounds in the solid state [X-ray diffraction] and gaseous states [electron diffraction], and mechanisms of reactions of transient silylenes and related species. In addition to the traditional metals and semimetals, elements such as selenium, lithium and magnesium are considered to form organometallic compounds, e.g. organomagnesium compounds MeMgI, iodo(methyl)magnesium and diethylmagnesium which are Grignard reagents an organo-lithium compound BuLi butyllithium; Organometallic compounds often find practical use as catalysts, the processing of petroleum products and the production of organic polymers.
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Specificații

ISBN-13: 9781600217791
ISBN-10: 1600217796
Pagini: 267
Ilustrații: b/w illus & tables
Dimensiuni: 189 x 267 x 24 mm
Greutate: 0.81 kg
Editura: Nova Science Publishers Inc

Cuprins

Preface; Cobalt Phosphine Complexes for the Polymerization of 1,3-dienes. Influence of the Phosphine Ligand on the Polymerization Chemo-and Steroselectivity; Half-Sandwich Ruthenium Complexes containing Water-Soluble Phosphine Ligands: Catalytic Applications; Electronic Properties of Transition Metal Carbene and Silylene Complexes- A Quantum Chemical Study at Selected Model Complexes; Activation of Alkynes by Camphor Complexes; The Chemistry of Organoimido Derivatives of Polyoxometalates Organic Chemistry as a Useful Tool for the Functionalization of POMs and the Preparation of Novel POM-Based Organic-Inorganic Hybrid Molecular Materials; Structural and Biological Chemistry of Organotin (IV) Complexes; The Role of Ionic Liquids in Palladium Catalyzed C-C Bond Forming Reactions; Making Crystals from Crystals: Methyl-Migrational Dismutation of Trimethyltin Complexes; Siloxane based Polymeric Structures containing Complexed Metals; Index.