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Block Copolymers in Solution – Fundamentals and Applications

Autor IW Hamley
en Limba Engleză Hardback – 27 iul 2005
A unique text discussing solution self-assembly of block copolymers, covering all aspects from basic physical chemistry to applications in soft nanotechnology. It covers the principles of self-assembly in both dilute and concentrated solution (micellization, mesophase formation etc).
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Specificații

ISBN-13: 9780470015575
ISBN-10: 0470015578
Pagini: 300
Dimensiuni: 152 x 229 x 20 mm
Greutate: 0.55 kg
Editura: Wiley
Locul publicării:Chichester, United Kingdom

Public țintă

Post–graduate and final year students, research assistants, researchers in academia and industry, scientists and engineers in chemical industry, academic libraries. Supplementary reading for general polymer science and technology courses for chemistry, physical chemistry, chemical physics, soft condensed matter students. Essential reading for courses specifically on block copolymers (e.g. M.Sc).

Cuprins

Preface Acknowledgements. Abbreviations. 1. Introduction. References. 2. Neutral Block Copolymers in Dilute Solution. 2.1 Introduction. 2.2 Techniques for Studying Micellization. 2.3 Micellization in PEO-based Block Copolymers. 2.4 Micellization in Styrenic Block Copolymers. 2.5 Determination of cmc. 2.6 Thermodynamics of Micellization. 2.7 Micellization and Micelle Dimensions: Theory and Simulation. 2.8 Micelle Dimensions: Comparison Between Experiment and Theory. 2.9 Interaction between Micelles. 2.10 Dynamics of Micellization. 2.11 Dynamic Modes. 2.12 Specific Types of Micelles. 2.13 Micellization in Mixed solvents. 2.14 Mixed micelles. 2.15 Block Copolymer/Surfactant complexes. 2.16 Complex Morphologies. 2.17 Vesicles. 2.18 Crystallization in Micelles. References. 3. Concentrated Solutions. 3.1 Understanding Phase Diagrams. 3.2 Phase Behaviour of PEO-containing Block Copolymers. 3.3 Gelation. 3.4 Order-Disorder Phase Transition. 3.5 Order-order Phase Transitions. 3.6 Domain Spacing Scaling, and Solvent Distribution profiles. 3.7 Semidilute Block Copolymer Solution Theory. 3.8 Theoretical understanding of Phase Diagrams. 3.9 Flow Alignment. 3.10 Dynamics. References. 4. Polyelectrolyte Block Copolymers. 4.1 Micellization. 4.2 Chain Conformation. 4.3 Theory. 4.4 Polyion Complexes. 4.5 Copolymer-surfactant complexes. 4.6 Complexation with other Molecules. 4.7 Gelation. 4.8 Hierarchical Order in Peptide Block Copolyelectrolyte Solutions. References. 5. Adsorption. 5.1 Introduction. 5.2 Adsorption at the Air-Water Interface. 5.3 Adsorption on Solid Substrates. 5.4 Surface Forces Experiments. 5.5 Modelling Adsorption. References. 6. Applications 6.1 Surfactancy/Detergency. 6.2 Solubilisation, Emusification and Stabilization. 6.3 Drug Delivery. 6.4 Biodegradable Block Copolymer Micelles. 6.5 Thermoresponsive Micellar Systems. 6.6 Metal-Containing Copolymer Micelles and Nanoreactors. 6.7 Vesicles. 6.8 Separation Media. 6.9 Templating. 6.10 Membranes. 6.11 Other Applications. References. Index.

Notă biografică

Ian W. Hamley is the author of Block Copolymers in Solution: Fundamentals and Applications, published by Wiley.