Carbosilanes: Syntheses and Reactions
Autor Gerhard Fritz, Eberhard Maternen Limba Engleză Paperback – 22 dec 2011
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Specificații
ISBN-13: 9783642708022
ISBN-10: 3642708021
Pagini: 276
Ilustrații: XII, 258 p.
Dimensiuni: 170 x 244 x 14 mm
Greutate: 0.45 kg
Ediția:Softcover reprint of the original 1st ed. 1986
Editura: Springer Berlin, Heidelberg
Colecția Springer
Locul publicării:Berlin, Heidelberg, Germany
ISBN-10: 3642708021
Pagini: 276
Ilustrații: XII, 258 p.
Dimensiuni: 170 x 244 x 14 mm
Greutate: 0.45 kg
Ediția:Softcover reprint of the original 1st ed. 1986
Editura: Springer Berlin, Heidelberg
Colecția Springer
Locul publicării:Berlin, Heidelberg, Germany
Public țintă
ResearchCuprins
I. Introduction.- 1. Characteristic Differences between the Elements Silicon and Carbon.- 2. Functional Groups in the Chemistry of Silicon.- II. The Formation of Carbosilanes.- 1. The Formation of Carbosilanes by Thermal Decomposition of Methylsilanes.- 2. Formation of Carbosilanes by Direct Reaction of Halogenomethanes with Silicon.- 3. Formation of Polycyclic Molecular Skeletons through Rearrangement of Carbosilanes with AlBr3 or AlCl3.- 4. Organometallic Syntheses of Carbosilanes.- III. Reactions of Carbosilanes.- 1. Introduction.- 2. The Introduction of New Functional Groups on the Carbosilane Molecular Skeleton.- 3. Reactions with MeMgCl and MeLi.- 4. Metallation of Carbosilanes.- 5. Reactions of C-Chlorinated Carbosilanes with Silylphosphanes.- 6. The Reactive Behavior of Further Cyclic Carbosilanes.- 7. Investigations into the Cleavage of Si —Me Bonds in Carbosilanes.- 8. Substituent Effects in Carbosilanes.- 9. Hydrosilylation in Carbosilane Chemistry.- IV. Results of Structural Investigations of Carbosilanes.- 1. X-Ray Investigations of Crystal Structures.- 2. Electron Diffraction Studies.- V. References.