Chlorine, Bromine and Iodine NMR: Physico-Chemical and Biological Applications: NMR Basic Principles and Progress, cartea 12
Autor B. Lindman, S. Forsenen Limba Engleză Paperback – feb 2012
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Specificații
ISBN-13: 9783642663659
ISBN-10: 3642663656
Pagini: 388
Ilustrații: XIV, 372 p.
Dimensiuni: 170 x 244 x 20 mm
Greutate: 0.62 kg
Ediția:Softcover reprint of the original 1st ed. 1976
Editura: Springer Berlin, Heidelberg
Colecția Springer
Seria NMR Basic Principles and Progress
Locul publicării:Berlin, Heidelberg, Germany
ISBN-10: 3642663656
Pagini: 388
Ilustrații: XIV, 372 p.
Dimensiuni: 170 x 244 x 20 mm
Greutate: 0.62 kg
Ediția:Softcover reprint of the original 1st ed. 1976
Editura: Springer Berlin, Heidelberg
Colecția Springer
Seria NMR Basic Principles and Progress
Locul publicării:Berlin, Heidelberg, Germany
Public țintă
ResearchCuprins
1. Introductory Aspects.- 1.1 General Properties of Halogens.- 1.2 Static Parameters.- 1.3 Dynamic Parameters.- 1.4 Chemical Exchange Effects.- 1.5 Experimental Aspects.- 2. Relaxation in Molecules or Ions With Covalently Bonded Halogens.- 2.1 Quadrupole Relaxation.- 2.2 Other Relaxation Mechanisms.- 3. Shielding Effects in Covalent Halogen Compounds.- 3.1 Theoretical Aspects.- 3.2 Experimental Data.- 3.3 Medium Effects on Halogen Shielding Constants.- 4. Scalar Spin Couplings.- 4.1 General Considerations.- 4.2 Experimental Data on Cl, Br and I Spin Couplings.- 5. Relaxation of Chloride, Bromide and Iodide Ions.- 5.1 Quadrupole Relaxation.- 5.2 Relaxation Rates and Chemical Shifts in Paramagnetic Systems.- 5.3 Chemical Exchange of Halide Ions.- 6. Shielding of Halide Ions.- 6.1 Absolute Shielding Values of Ions in Aqueous Solutions.- 6.2 Shielding in Aqueous Alkali Halide Solutions.- 6.3 Shielding in Other Aqueous Solutions.- 6.4 Shielding in Mixed Solvent and Non-Aqueous Solution.- 6.5 Water Solvent Isotope Effect on Shielding.- 7. Quadrupole Splittings in Liquid Crystals.- 7.1 General Aspects on Static Quadrupole Effects of Mesomorphous Systems.- 7.2 Halogen Quadrupole Splittings of Covalent Compounds in Liquid Crystals.- 7.3 Quadrupole Splittings of Halide Ions in Amphiphilic Mesophases.- 8. Halide Ions in Biological Systems.- 8.1 General Principles.- 8.2 Small Molecules or Ions of Biological Interest.- 8.3 Polypeptides.- 8.4 Proteins.- 8.5 Miscellaneous Systems.- 9. Studies of the Perchlorate Ion.- 9.1 Introduction.- 9.2 Shielding.- 9.3 Quadrupole Effects.- 10. Recent Work.- 11. References.- 12. Subject Index.