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Chromium -VI Reagents: Synthetic Applications: SpringerBriefs in Molecular Science

Autor S. Sundaram, P. S. Raghavan
en Limba Engleză Paperback – 12 aug 2011
Chromic acid and chromium oxide are the two versatile Cr(VI) oxidants known to organic chemists for decades. The introduction of the Core's reagent , viz: pyridinium chlorochromate, in 1975 followed by the publications on several Cr(VI) oxidizing agents containing the -onium chromates and halochromates in the last three decades have very much changed the chemistry of oxidations with Chromium VI. Several of these new reagents have been shown to be mild so that they can be handled easily and the reacton products may also be controlled. Some of them are highly selective oxidants for positions like allylic hydroxylic group, etc., and some other are highly regioselective. The information on more than 36 such reagents reported in various internationally reputed journals spanning about 280 references have been collected and provided in this book in such a manner that it will be very useful for professionals, researchers, teachers and graduate students working in organic synthesis.
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Specificații

ISBN-13: 9783642208164
ISBN-10: 3642208169
Pagini: 60
Ilustrații: XII, 66 p. 59 illus.
Dimensiuni: 155 x 235 x 7 mm
Greutate: 0.11 kg
Ediția:2011
Editura: Springer Berlin, Heidelberg
Colecția Springer
Seria SpringerBriefs in Molecular Science

Locul publicării:Berlin, Heidelberg, Germany

Public țintă

Research

Cuprins

Introduction.- Reagent classification.- Synthetic strategies.- Kinetic aspects.- Solid supported Cr(VI) reagents.- Chromium in Biology.

Textul de pe ultima copertă

Chromic acid and chromium oxide are the two versatile Cr(VI) oxidants known to organic chemists for decades. The introduction of the Core's reagent , viz: pyridinium chlorochromate, in 1975 followed by the publications on several Cr(VI) oxidizing agents containing the -onium chromates and halochromates in the last three decades have very much changed the chemistry of oxidations with Chromium VI. Several of these new reagents have been shown to be mild so that they can be handled easily and the reacton products may also be controlled. Some of them are highly selective oxidants for positions like allylic hydroxylic group, etc., and some other are highly regioselective. The information on more than 36 such reagents reported in various internationally reputed journals spanning about 280 references have been collected and provided in this book in such a manner that it will be very useful for professionals, researchers, teachers and graduate students working in organic synthesis.

Caracteristici

Latest research results in the mentioned field