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Cyclic Ss-Ketoesters

Autor M A Metwally, E. G. Sadek
en Limba Engleză Paperback – 30 iun 2010
The chemistry of cyclic ß-ketoesters has received considerable attention because they serve as highly important intermediates in many organic synthesis. The wide application of these compounds in organic synthesis, depends chiefly on the reactivity of the methylene group, and the ready hydrolysis of the ester group, and its substituted derivatives to carboxlic acids and ketones. The syntheses and reactions of cyclic ß-ketoesters are reviewed in a formal way.
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Specificații

ISBN-13: 9781616682828
ISBN-10: 1616682825
Pagini: 111
Ilustrații: b/w illus
Dimensiuni: 153 x 228 x 8 mm
Greutate: 0.2 kg
Editura: Nova Science Publishers Inc
Locul publicării:United States

Cuprins

Carboxylation of ketones; Intramolecular condensation & cyclization of Six-membered rings; Isomerization; Dieckmann condensation (intramolecular Claisen condensation); Miller & Nord Reaction:; Esters of *,*-diethylacetonedicarboxylic acid; Cyclic *-keto esters from cyclic ketones & ethyl cyanoacetate; Claisen acylation & carboethoxylation of ketones & esters; Homologation of ketones with ethyl diazoacetate; Synthesis of carboethoxycyclohexanone; Synthesis of carboethoxycyclohexanone; The enamine acylation & alkylation of carbonyl compound; Synthesis of 2-Carboethoxycyclohexanone; Synthesis of N-containing cyclic Ò-keto esters; Synthesis of Ñ,Ñ-Difluoro-Ò-ketoesters.