Dipole-Quadrupole Theory of Surface Enhanced Raman Scattering
Autor A.M. Polubotkoen Limba Engleză Paperback – 4 mai 2009
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Specificații
ISBN-13: 9781606925799
ISBN-10: 1606925792
Pagini: 136
Ilustrații: tables
Dimensiuni: 182 x 253 x 4 mm
Greutate: 0.33 kg
Editura: Nova Science Publishers Inc
ISBN-10: 1606925792
Pagini: 136
Ilustrații: tables
Dimensiuni: 182 x 253 x 4 mm
Greutate: 0.33 kg
Editura: Nova Science Publishers Inc
Cuprins
Preface; Introduction; Main Specific Features of the SERS phenomenon; Some of the Existing Theories; Some Properties of the Electromagnetic Field Near a Rough Metal Surface; Expressions for the SER Cross-Sections of Arbitrary and Symmetrical Molecules; Selection Rules For Symmetrical Molecules; Classification of the Contributions by the Degree of Enhancement; Most Enhanced Bands in SERS; (dz-Qmain), (Qmain-dz) and (dz-dz) Contributions and Appearance of Forbidden Bands in the SER Spectra of Symmetrical Molecules; Contributions Caused by One Minor and One Main Moments; Disturbance of the Symmetry of Molecules Upon Adsorption and Two Possible Mechanisms of the Appearance of Forbidden Bands in the SER Spectra; Analysis of the SER Spectra; Analysis of the SER Spectra of Molecules With and Symmetry Groups; Anomalies in the SER Spectra of Benzene Adsorbed on Lithium and Hexafluorobenzene Adsorbed on Silver; Electrodynamic Forbiddance of the Quadrupole Enhancement Mechanism in Molecules with Cubic Symmetry Groups; Discussion of Experimental Results; About the Electrodynamic Forbiddance of the Quadrupole SERS Mechanism in Other Molecules; Anomalies of the SER Spectra of Symmetrical Molecules Adsorbed on Transition Metal Substrates; Possible Reason of the Competition of the Raman Bands (Influence of the Complex Dielectric Constant); Single Molecule Detection by the SERS Method and Its Relation to the Quadrupole SERS Theory; Charge Transfer Enhancement Mechanism; Explanation of Experimental Phenomena Accompanying SERS; Conclusion; Appendix 1 Wave functions of Arbitrary Molecules; Appendix 2 The Tables of Irreducible Representations of Some Point Groups; References; Index.