Free Energy Relationships in Organic and Bio-Organic Chemistry: Rsc
Autor Andrew Williamsen Limba Engleză Paperback – 31 aug 2003
Introducing the application of free energy correlations to elucidating the mechanisms of organic and bio-organic reactions, this book provides a new and illuminating way of approaching a potentially complex topic. The idea of how free energy correlations derive from polar substituent change is introduced, and common pitfalls encountered in the application of free energy relationships are described, along with the use of these anomalies in mechanistic studies. The concept of effective charge is described in detail, with examples of its application. Throughout, worked answers are provided for the problems posed. Databases of parameters, an extensive bibliography and comprehensive lists of further reading are also included. The text provides an invaluable source of information to senior undergraduates, postgraduates and to industrial researchers with an interest in mechanistic studies. It is the first such book in more than thirty years.
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Specificații
ISBN-13: 9780854046768
ISBN-10: 0854046763
Pagini: 290
Ilustrații: 1
Dimensiuni: 160 x 235 x 17 mm
Greutate: 0.48 kg
Editura: Royal Society Of Chemistry
Locul publicării:United Kingdom
ISBN-10: 0854046763
Pagini: 290
Ilustrații: 1
Dimensiuni: 160 x 235 x 17 mm
Greutate: 0.48 kg
Editura: Royal Society Of Chemistry
Locul publicării:United Kingdom
Cuprins
Free Energy Relationships; The Equations; Effective Charge; Multiple Interactions to the Reaction Centre; Anomalies and Special Cases; Coupling Between Bonds in Transition States of Displacement Reactions; Applications; Answers to Problems; Summary of Equations; Tables of Constants; Some Linear Free Energy Equations.
Descriere
The text provides an invaluable source of information to senior undergraduates, postgraduates and to industrial researchers with an interest in mechanistic studies.