Fundamental Coordination Ability of s-Block Metal Ions: New Aspects and Its Role in Solution Reactions
Editat de Masashi Hojoen Limba Engleză Paperback – oct 2025
- Features information on direct chemical interaction between s-block metal ions and anions in solution
- Includes details on the activities of ions in solution, and a discussion of the effects of lower vs higher ionic strength media
- Covers enhanced oxidation ability of dilute nitric acid
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Specificații
ISBN-13: 9780443290138
ISBN-10: 044329013X
Pagini: 350
Dimensiuni: 152 x 229 mm
Editura: ELSEVIER SCIENCE
ISBN-10: 044329013X
Pagini: 350
Dimensiuni: 152 x 229 mm
Editura: ELSEVIER SCIENCE
Cuprins
Part I: Chemical interaction above electrostatic force between s-block metals and ligand ions 1. Host-Guest Chemistry of s-Block Metal Ions and the Development of Supramolecule Chemistry Part II: The Development of Supramolecular Chemistry Systems 2. Light Metal Coordination Polymers 3. Voltammetric Studies on Chemical Interactions of Alkali Metal Ions with Acetate and Benzoate Ions in Acetonitrile 4. Salt Effects on Proton Transfer from Nitrophenols to Amine or Pyridine Bases in Acetonitrile 5. Elucidation of Salt Effects on the Indicator Acidity in Acetonitrile 6. Direct Chelate Formation between Alkaline Earth Metal Ions and 1-(2-Pyridylazo)-2-naphthol and Related Reactions in Acetonitrile 7. Higher Ion–Aggregates in Low Permittivity Media 8. Conductivity and Spectroscopic Studies of Ion Aggregates in Higher Permittivity Media Part III: Coordination phenomena of s-block metal ions in aprotic and protic solvents 9. UV–Visible and {sup|1}H or {sup|13}C NMR Spectroscopic Studies on the Specific Interaction between Lithium and Tropolonate Ions in Acetonitrile or Other Solvents 10. Interaction between Protons or Alkaline Earth Metal Ions and the Benzoate Ion in Acetonitrile Studied by UV–visible, {sup|1}H and {sup|13}C NMR Spectroscopy 11. Precipitation and Re-Dissolution of s-Block Metal Salts Based on Coordination and “Reverse Coordination” with Aromatic Dicarboxylate, Sulfonate, or Disulfonate ions in Acetonitrile 12. Specific Coordination Phenomena of Alkaline Earth Metal Ions with Mono-, Di-, and Trisulfonates in Alcohols and Binary Solvents 13. Strong Complexing Ability of Alkali Metal and Alkaline Earth Metal Ions with Organic Phosphinate and Phosphates 14. Chemical Interaction between Alkaline Earth Metal Ions and the Benzoate or 2,6-Naphthalenedicarboxylate Ion in Acetonitrile and Alcohols 15. Coordination and “Reverse Coordination” of Alkali Metal, Alkaline Earth Metal, and Indium Ions with 1,3,6-Naphthalenetrisulfonate Ion in Protic and Aprotic Solvents Part IV: Application of the coordination ability of s-block metals and related reactions in solution 16. {sup|1}H and {sup|13}C NMR Detection of the Carbocations or Zwitterions from Fluoran Leuco Dyes or Trityl Chlorides on the Addition of s-Block Metal Ions 17. Alternative Mechanism of S{sub|N}1 Solvolysis Based on the Direct Chemical Interaction between s-Block Metal Cations and Leaving–Group Anions 18. Discovery of Enhanced Oxidation Mechanism of Dilute Nitric Acid (and Pure Gold Dissolution in Seawater) 19. Pure Gold Dissolution by the Oxidation Ability of Dilute Nitric and Nitrous Acids in the Presence of Abundant Metal Salts 20. Pure Gold and Stainless Steel Dissolution or Corrosion in Dilute Halic Acids (HXO{sub|3}, X = Cl, Br, I) Solution containing Abundant Halide Ions 21. Elucidation of Specific Ion Association in Nonaqueous Solution Environments