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High–Performance Materials from Bio–based Feedstocks de AJ Hunt

High–Performance Materials from Bio–based Feedstocks: Wiley Series in Renewable Resource

Autor AJ Hunt
en Limba Engleză Hardback – 27 apr 2022
High-Performance Materials from Bio-based Feedstocks High-Performance Materials from Bio-based Feedstocks The latest advancements in the production, properties, and performance of bio-based feedstock materials In High-Performance Materials from Bio-based Feedstocks, an accomplished team of researchers delivers a comprehensive exploration of recent developments in the research, manufacture, and application of advanced materials from bio-based feedstocks. With coverage of bio-based polymers, the inorganic components of biomass, and the conversion of biomass to advanced materials, the book illustrates the research and commercial potential of new technologies in the area. Real-life applications in areas as diverse as medicine, construction, synthesis, energy storage, agriculture, packaging, and food are discussed in the context of the structural properties of the materials used. The authors offer deep insights into materials production, properties, and performance. Perfect for chemists, environmental scientists, engineers, and materials scientists, High-Performance Materials from Bio-based Feedstocks will also earn a place in the libraries of academics, industrial researchers, and graduate students with an interest in biomass conversion, green chemistry, and sustainability. * A thorough introduction to the latest developments in advanced bio-based feedstock materials research * Comprehensive explorations of a vast range of real-world applications, from tissue scaffolds and drug delivery to batteries, sorbents, and controlled release fertilizers * Practical discussions of the organic and inorganic components of biomass and the conversion of biomass to advanced materials * In-depth examinations of the structural properties of commercially and academically significant biomass materials For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs
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Specificații

ISBN-13: 9781119655725
ISBN-10: 1119655722
Pagini: 432
Dimensiuni: 176 x 245 x 29 mm
Greutate: 0.88 kg
Editura: Wiley
Seria Wiley Series in Renewable Resource

Locul publicării:Chichester, United Kingdom

Cuprins

Series Preface xxi 1 High-performance Materials from Bio-based Feedstocks: Introduction and Structure of the Book 1 Kaewta Jetsrisuparb, Jesper T.N. Knijnenburg, Nontipa Supanchaiyamat and Andrew J. Hunt 1.1 Introduction 1 1.2 High-performance Bio-based Materials and Their Applications 4 1.2.1 Biomass Constituents 4 1.2.2 Bioderived Materials 7 1.3 Structure of the Book 10 2 Bio-based Carbon Materials for Catalysis 13 Chaiyan Chaiya and Sasiradee Jantasee 2.1 Introduction 13 2.2 Biomass Resources for Carbon Materials 14 2.2.1 Wood from Natural Forests 14 2.2.2 Agricultural Residues 17 2.3 Thermochemical Conversion Processes 18 2.3.1 Carbonization and Pyrolysis 18 2.3.2 Activation 20 2.3.3 Hydrothermal Carbonization 23 2.3.4 Graphene Preparation from Biomass 24 2.4 Fundamentals of Heterogeneous Catalysis 25 2.5 Catalysis Applications of Selected Bio-based Carbon Materials 26 2.5.1 Biochar 26 2.5.2 Modified Biochar 28 2.5.3 Biomass-Derived Activated Carbon 30 2.5.4 Hydrothermal Bio-based Carbons 34 2.5.5 Sugar-Derived Carbon Catalysts 35 2.5.6 Carbon Nanotubes from Biomass 36 2.5.7 Graphene and Its Derivatives 37 2.6 Summary and Future Aspects 37 3 Starbon(r): Novel Template-Free Mesoporous Carbonaceous Materials from Biomass - Synthesis, Functionalisation and Applications in Adsorption, and Catalysis 47 Duncan J. Macquarrie, Tabitha H.M. Petchey and Cinthia J. Meña Duran 3.1 Introduction 47 3.2 Choice of Polysaccharide 48 3.2.1 Synthetic Procedure 49 3.2.2 Derivatisation 51 3.2.3 Applications 56 3.2.4 Adsorption Processes 63 3.2.5 Conclusion 69 4 Conversion of Biowastes into Carbon-based Electrodes 73 Xiaotong Feng and Qiaosheng Pu 4.1 Introduction 73 4.2 Conversion Techniques of Biowastes 74 4.2.1 Carbonization 75 4.2.2 Activation 77 4.3 Structure and Doping 79 4.3.1 Biowaste Selection 79 4.3.2 Structure Control 81 4.3.3 Heteroatom Doping 83 4.4 Electrochemical Applications 84 4.4.1 Supercapacitors 84 4.4.2 Capacitive Deionization Cells 86 4.4.3 Hydrogen and Oxygen Evolution 88 4.4.4 Fuel Cells 90 4.4.5 Lithium-Ion Batteries and Others 94 4.5 Conclusion and Outlook 95 5 Bio-based Materials in Electrochemical Applications 105 Itziar Iraola-Arregui, Mohammed Aqil, Vera Trabadelo, Ismael Saadoune and Hicham Ben Youcef 5.1 Introduction 105 5.2 Fundamentals of Bio-based Materials 106 5.2.1 Bio-based Polymers 106 5.2.2 Carbonaceous Materials from Biological Feedstocks 108 5.3 Application of Bio-based Materials in Batteries 109 5.3.1 General Concept of Metal-Ion Batteries 109 5.4 Application of Bio-based Polymers in Capacitors 115 5.4.1 General Concept of Electrochemical Capacitors 115 5.4.2 Electrode Materials 116 5.5 Alternative Binders for Sustainable Electrochemical Energy Storage 119 5.5.1 Polysaccharides and Cellulose-based Binders 120 5.5.2 Lignin 123 5.6 Application of Bio-based Polymers in Fuel Cells 123 5.6.1 Chitosan 124 5.6.2 Other Biopolymers 125 5.7 Conclusion and Outlook 126 6 Bio-based Materials Using Deep Eutectic Solvent Modifiers 133 Wanwan Qu, Sarah Key and Andrew P. Abbott 6.1 Introduction 133 6.2 Bio-based Materials 134 6.2.1 Ionic Liquids 136 6.2.2 Deep Eutectic Solvents 136 6.2.3 Morphological/Mechanical Modification 137 6.2.4 Chemical Modification 139 6.2.5 Composite Formation 141 6.2.6 Gelation 143 6.3 Conclusion 145 7 Biopolymer Composites for Recovery of Precious and Rare Earth Metals 151 Jesper T.N. Knijnenburg and Kaewta Jetsrisuparb 7.1 Introduction 151 7.2 Mechanisms of Metal Adsorption 153 7.2.1 Silver 153 7.2.2 Gold and Platinum Group Metals 153 7.2.3 Rare Earth Metals 154 7.3 Composite Materials and Their Adsorption 154 7.3.1 Cellulose-based Composite Adsorbents 154 7.3.2 Chitosan-based Composite Adsorbents 163 7.3.3 Alginate-based Adsorbents 170 7.3.4 Lignin-based Composite Adsorbents 173 7.4 Conclusion and Outlook 175 8 Bio-Based Materials in Anti-HIV Drug Delivery 181 Oranat Chuchuen and David F. Katz 8.1 Introduction 181 8.2 Biomedical Strategies for HIV Prophylaxis 182 8.3 Properties of Anti-HIV Drug Delivery Systems 184 8.4 Bio-based Materials for Anti-HIV Drug Delivery Systems 185 8.4.1 Cellulose 186 8.4.2 Chitosan 190 8.4.3 Polylactic Acid 191 8.4.4 Carrageenan 193 8.4.5 Alginate 194 8.4.6 Hyaluronic Acid 195 8.4.7 Pectin 196 8.5 Conclusion 196 9 Chitin - A Natural Bio-feedstock and Its Derivatives: Chemistry and Properties for Biomedical Applications 207 Anu Singh, Shefali Jaiswal, Santosh Kumar and Pradip K. Dutta 9.1 Bio-feedstocks 207 9.1.1 Chitin 208 9.1.2 Chitosan 208 9.1.3 Glucan 209 9.1.4 Chitin-Glucan Complex 209 9.1.5 Polyphenols 209 9.2 Synthetic Route 210 9.2.1 Isolation of ChGC 210 9.2.2 Derivatives of ChGC and Its Modified Polymers 210 9.2.3 Preparation of d-Glucosamine from Chitin/Chitosan-Glucan 212 9.3 Properties of Chitin, ChGC, and Its Derivatives for Therapeutic Applications 212 9.3.1 Antibacterial Activity 212 9.3.2 Anticancer Activity 212 9.3.3 Antioxidant Activity 212 9.3.4 Therapeutic Applications 213 9.4 Gene Therapy - A Biomedical Approach 213 9.5 Cs: Properties and Factors Affecting Gene Delivery 214 9.6 Organic Modifications of Cs Backbone for Enhancing the Properties of Cs Associated with Gene Delivery 215 9.6.1 Modification of Cs with Hydrophilic Groups 215 9.6.2 Modification in Cs by Hydrophobic Groups 216 9.6.3 Modification by Cationic Substituents 216 9.6.4 Modification by Target Ligands 217 9.7 Multifunctional Modifications of Cs 218 9.8 Miscellaneous 218 9.9 Conclusion 218 10 Carbohydrate-Based Materials for Biomedical Applications 235 Chadamas Sakonsinsiri 10.1 Introduction 235 10.2 Bio-based Glycopolymers 236 10.2.1 Chitin and Chitosan 236 10.2.2 Cellulose 238 10.2.3 Starch 239 10.2.4 Dextran 239 10.3 Synthetic Carbohydrate-based Functionalized Materials 240 10.3.1 Glycomimetics 240 10.3.2 Presentation of Glycomimetics in Multivalent Scaffolds 241 10.4 Conclusion 243 11 Organic Feedstock as Biomaterial for Tissue Engineering 247 Poramate Klanrit 11.1 Introduction 247 11.2 Protein-based Natural Biomaterials 248 11.2.1 Silk 249 11.2.2 Collagen 249 11.2.3 Decellularized Skins 251 11.2.4 Fibrin/Fibrinogen 252 11.3 Polysaccharide-based Natural Biomaterials 253 11.3.1 Chitosan 253 11.3.2 Alginate 254 11.3.3 Agarose 255 11.4 Summary 255 12 Green Synthesis of Bio-based Metal-Organic Frameworks 261 Emile R. Engel, Bernardo Castro-Dominguez and Janet L. Scott 12.1 Introduction 261 12.2 Green Synthesis of MOFs 262 12.2.1 Solvent-Free and Low Solvent Synthesis 262 12.2.2 Green Solvents 264 12.2.3 Sonochemical Synthesis 266 12.2.4 Electrochemical Synthesis 266 12.3 Bio-based Ligands 266 12.3.1 Amino Acids 266 12.3.2 Aliphatic Diacids 267 12.3.3 Cyclodextrins 269 12.3.4 Other 270 12.3.5 Exemplars: Bio-based MOFs Obtainable via Green Synthesis 271 12.4 Metal Ion Considerations 271 12.4.1 Calcium 272 12.4.2 Magnesium 272 12.4.3 Manganese 273 12.4.4 Iron 273 12.4.5 Titanium 274 12.4.6 Zirconium 274 12.4.7 Aluminium 275 12.4.8 Zinc 275 12.5 Challenges for Further Development Towards Applications 276 12.5.1 Stability Issues 276 12.5.2 Scalability and Cost 278 12.5.3 Competing Alternative Materials 279 12.6 Conclusion 280 13 Geopolymers Based on Biomass Ash and Bio-based Additives for Construction Industry 289 Prinya Chindaprasirt, Ubolluk Rattanasak and Patcharapol Posi 13.1 Introduction 289 13.2 Pozzolan and Agricultural Waste Ash 290 13.3 Geopolymer 292 13.4 Combustion of Biomass 294 13.4.1 Open Field Burning 294 13.4.2 Controlled Burning 294 13.4.3 Boiler Burning 294 13.4.4 Fluidized Bed Burning 295 13.5 Properties and Utilization of Biomass Ashes 295 13.6 Biomass Ash-based Geopolymer 299 13.6.1 Rice Husk Ash-based Geopolymer 300 13.6.2 Bagasse Ash-based Geopolymer 304 13.6.3 Palm Oil Fuel Ash-based Geopolymer 306 13.6.4 Other Biomass-based Geopolymers 308 13.6.5 Use of Biomass in Making Sodium Silicate Solution and Other Products 308 13.6.6 Fire Resistance of Bio-based Geopolymer 309 13.7 Conclusion 309 14 The Role of Bio-based Excipients in the Formulation of Lipophilic Nutraceuticals 315 Alexandra Teleki, Christos Tsekou and Alan Connolly 14.1 Introduction 315 14.2 Emulsions and the Importance of Bio-based Materials as Emulsifiers 316 14.2.1 Conventional Micro-and Nanoemulsions 316 14.2.2 Pickering-Stabilised Emulsions 319 14.3 Novel Formulation Technologies: Colloidal Delivery Vesicles 320 14.3.1 Microgels 320 14.3.2 Nanoprecipitation 321 14.3.3 Liposomes 322 14.3.4 Complex Coacervation 323 14.3.5 Complexation 325 14.4 Key Drying Technologies Employed During Formulation 325 14.4.1 Spray Drying 325 14.4.2 Spray-Freeze Drying 327 14.4.3 Electrohydrodynamic Processing 328 14.4.4 Fluid Bed Drying 329 14.4.5 Extrusion 329 14.5 Conclusions and Future Perspectives 330 15 Bio-derived Polymers for Packaging 337 Pornnapa Kasemsiri, Uraiwan Pongsa, Manunya Okhawilai, Salim Hiziroglu, Nawadon Petchwattana, Wilaiporn Kraisuwan and Benjatham Sukkaneewat 15.1 Introduction 337 15.2 Starch 338 15.3 Chitin/Chitosan 340 15.4 Cellulose and Its Derivatives 342 15.4.1 Cellulose Nanocrystals 343 15.4.2 Cellulose Nanofibers 343 15.4.3 Bacterial Nanocellulose 344 15.4.4 Carboxymethyl Cellulose 344 15.5 Poly(Lactic Acid) 345 15.5.1 Bio-based Toughening Agents Used in PLA Toughness Improvement 346 15.5.2 Toughening of PLA and Its Properties Related to Packaging Applications 346 15.6 Bio-based Active and Intelligent Agents for Packaging 348 15.6.1 Active Agents 348 15.6.2 Intelligent Packaging 351 15.7 Conclusion 351 16 Recent Developments in Bio-Based Materials for Controlled-Release Fertilizers 361 Kritapas Laohhasurayotin, Doungporn Yiamsawas and Wiyong Kangwansupamonkon 16.1 Introduction and Historical Review 361 16.1.1 Early Fertilizer Development and Its Impact on Environment 361 16.1.2 Controlled-Release Fertilizer 362 16.2 Mechanistic View of Controlled-Release Fertilizer from Bio-based Materials 365 16.2.1 Coating Type 366 16.2.2 Matrix Type 367 16.2.3 Other Release Mechanisms 368 16.3 Controlled Release Technologies from Bio-based Materials 368 16.3.1 Natural Polymers and Their Fertilizer Applications 369 16.3.2 Bio-based Modified Polymer Coatings for Controlled-Release Fertilizer 376 16.3.3 Biochar and Other Carbon-based Fertilizers 380 16.4 Conclusion and Foresight 385 Index 399