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Inorganic Polymers Containing -Re(CO)3L+ Pendants de Ezequiel Wolcan

Inorganic Polymers Containing -Re(CO)3L+ Pendants

Autor Ezequiel Wolcan, Mario R. Feliz
en Limba Engleză Paperback – 7 feb 2011
This book describes the synthesis, photophysical and photochemical properties of inorganic polymers containing-Re(CO)3L+ pendants. Marked differences were found between the photochemical and photophysical properties of the polymers and those of the related monomeric complexes, pyRe(CO)3L+ (py = pyridine). The main cause of these differences is the photogeneration of the metal-to-ligand charge transfer (MLCT) excited sates in concentrations that are much larger when -Re(CO)3 L+ chromophores are bound to (vpy)n~600.
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Specificații

ISBN-13: 9781616689285
ISBN-10: 1616689285
Pagini: 84
Ilustrații: tables & charts
Dimensiuni: 153 x 228 x 7 mm
Greutate: 0.16 kg
Editura: Nova Science Publishers Inc

Cuprins

Introduction; Synthesis of the Polymers; Solvent Effects on Morphologies: Nanoaggregation; Photophysical Properties of Polymer (I); Laser Power, Thermal & Solvent Effects on the Photophysical Properties of Polymer (II); Binding of Cu(II) E Species to Polymer (II); Luminescence Quenching by Cu(II); Theoretical Outline of Fluorescence Resonance Energy Transfer (FRET) in Polymers; Resonance Energy Transfer in the Solution Phase Photophysics of Polymers (VII)-(IX); Contrasting Intrastrand Photoinduced Processes in Macromolecules Containing Pendant -Re(CO)3(1,10-phenanthroline)+: Electron versus Energy Transfer in Polymers (I) & (X); Conclusions; Index.