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Kinetics and Thermodynamics for Chemistry and Biochemistry

Editat de Eli M. Pearce, G. E. Zaikov
en Limba Engleză Hardback – 12 mai 2009
This is the second volume of works of Prof. Gennady Efremovich Zaikov and his colleagues dedicates to 75th anniversary of his birth. The first volume had the title "Progress in chemistry and biochemistry. Kinetics, thermodynamics, synthesis, properties and applications". Reviews and original works are devoted to different aspects of polymerisation (kinetics and mechanism), to preparation of nanocomposites on the basis of clays, to studying of their properties and searches of ways of their applications, oxidising processes, the new equipments for industrial applications, investigation of protein reactions, creation of new type of reactions, bioantioxidants, UV irradiation of biological molecules (erythrocytes, particularly), NMR- and ESR-spectroscopy, non-equilibrium phase transitions, chemistry of plastics and rubbers, photochemical reactions, preparation and characterisation of catalysts, industrial installations, cement-based polymer composites, utilisation of waste, diffusion properties, biodegradable films. Part of the research also deals with degradation and stabilisation of polymers. It is very important to prolong the time of reliable exploitation of polymeric products, but sometimes it is important to accelerate degradation of polymer (especially after the end of its period of exploitation). The experts consider that full degradation of one plastic bag will finish in 400 years (though nobody has witness it) after the beginning of operation. Aging of polymers depends on their stabilisation.
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Specificații

ISBN-13: 9781606923528
ISBN-10: 1606923528
Pagini: 468
Ilustrații: tables & charts
Dimensiuni: 184 x 258 x 34 mm
Greutate: 1.14 kg
Editura: Nova Science Publishers Inc

Cuprins

Preface; Professor Gennady Efremovich Zaikov in his office (November 2007). Right and up from him is poster of his teacher Prof. Nikolai Markovich Emanuel. Up from him is picture of his grandson Denis when he was six years old (it is not picture of Pablo Picasso). Left from him is portrait of Prof. Robert A. Karakhanov (1933-2001) who was student with Zaikov in the same group; Regularities of photoinitiated copolymerization of (meth)acrylates till high conversions. Kinetic model of the process at linear chain termination; Preparation and characterization of metal silicates: review; Development of possible stationary states identification method in industrial reactive distillation processes; The new type of nonequilibrium phase transition in differing nature systems with low-coupled magnetic moments; Effect of UV irradiation on erythrocytes in the presence of antioxidants-containing silica; Interactions between prion proteins and molecular chaperones by the example of ovine prion variants VRQ and ARR and chaperonin groel; Optimization of dichloroacetic acids hydrogenation reactor; Rubber-tire particles as concrete aggregate; Experimental Investigation on cement-based composite containing polypropylene fibers exposed to high temperature; Polymer Research institute. Celebration of 60 years in education and research (1947-2007); The new equipment for clearing industrial emissions; Simulation of organic compound oxidation on the surfaces of iron and chromium nanoclusters; Kinetics and molecular modelling of 1-hydroxycyclohexyl hydroperoxide decomposion 1-activated by Alk4NBr; Effects of polypropylene fibers on expansion properties of cement based composite containing waste glass; Water interaction of biodegradable films based on composition of polyhydroxybutyrate / polyamide resin; Partial replacement of aggregates by recycled polymer fibers in cement-matrix composites; Release of volatile compounds from bread; Impact of transition metals in the free-radical degradation of hyaluronan biopolymer; Hyaluronan degradation by ascorbate: protective effects of manganese(II) chloride; A.K. Haghi "Polypropylene and natural fibers for stabilization of soil-cement composites"; New condensation monomers and polymers based on TNT-derivatives; Influence of porphyrin and its metal complexes on the radical polymerization of methyl methacrylate; Synthesis and use of new ferrocenecontaining catalysts and plasticisers for burning of the solid fuels of special purpose; Analysis of solvents properties influence on kinetics of some homolytic reactions; The influence of medium on the thermolysis of diacyl and dialkylperoxides; The influence of the solvents on hydroperoxides decomposition and the reactions of phenoxy radicals decay; Solvents effects in oxidation reactions; The medium influence on different homolytic reactions; Degradation of low density polyethylene/starch blends under an enzymatic complex or soil microorganisms action; Retention of odorants by maltodextrins during storage; Quantum-chemical calculation of molecules a- and ß- glucose by method AB INITIO; AB INITIO study of cis-trans-isomerisation of molecules with double bonds; G.E. Zaikov and his wife Dr. Marina Artsis in Bangkok, January 2008; Index.