Metal–Organic Frameworks with Heterogeneous Structures

Ali Morsali is Master in inorganic chemistry at Tarbiat Modares University, Tehran, Iran. He obtained his PhD in 2003 in inorganic chemistry from the same university. He has published more than 400 articles in international journals as well as 5 patents and published 4 books under the Wiley-Scrivener imprint. He has received numerous national awards. Amongst his research interests are coordination chemistry and metal-organic frameworks. Kayhaneh Berijani earned her PhD in inorganic chemistry from the University of Zanjan. After graduating, she worked as a postdoctoral researcher with Prof. Ali Morsali on chiral MOFs field at Tarbiat Modares University. Her current research interests are chiral metal-organic frameworks, green chemistry, chiral materials and asymmetric processes.

List of Illustrations vii List of Tables xv List of Schemes xvii Preface xix Abbreviations xxi 1 Introduction: A Brief Introduction About Metal-Organic Frameworks 1 1.1 Metal-Organic Frameworks 1 1.2 Conclusion 8 References 8 2 Metal-Organic Frameworks Complexity 13 2.1 Perspectives on Complexity in MOFs 13 2.2 Conclusion 21 References 22 3 Complexity Based on Ligand--Part 1 27 3.1 Mixed Ligand 27 3.2 Conclusion 50 References 51 4 Complexity Based on Ligand--Part 2 57 4.1 Polytopic Linkers 57 4.2 Multi-Heterotopic Ligands 63 4.3 Conclusion 66 References 66 5 Complexity Based on Metal Node 71 5.1 Mixed Metal 71 5.2 Multiple SBUs 81 5.3 Conclusion 92 References 92 6 Complexity Based on Chiral Framework--Part 1 105 6.1 Inherent Chirality 105 6.2 Direct Chirality 109 6.3 Conclusion 120 References 121 7 Complexity Based on Chiral Framework--Part 2 127 7.1 Chiral-Template Synthesis 127 7.2 Post-Synthesis 131 7.3 Conclusion 144 References 144 8 Complexity Based on Structural Defects 149 8.1 Inherent Defect 149 8.2 Designed Defect 154 8.3 Conclusion 161 References 162 9 Complexity Based on Heterogeneous Pores 171 9.1 Heterogeneous Pores 171 9.2 Conclusion 178 References 179 10 Complexity Based on Mixed MOFs 185 10.1 Complex Mixed MOFs 185 10.2 Conclusion 192 References 193 Index 199