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Non-Phosgene Polycarbonate from CO2 - Industrialization of Green Chemical Process

Autor Shinsuke Fukuoka
en Limba Engleză Hardback – 30 sep 2011
The world's first non-phosgene process for producing an aromatic polycarbonate (PC) using CO2 as a starting material has been succeeded in development and industrialization by Asahi Kasei Corporation, Japan. The new process is not only environmentally friendly, but also economically superior to the current processes. All polycarbonate (PC) in the world have been produced using CO as a starting material until the new process was industrialized in 2002; among them, more than about 90% of polycarbonate (PC) have been produced by the so-called phosgene process. The phosgene process must use not only highly toxic and corrosive phosgene (COCl2) made from CO and Cl2, but also large quantities of solvents, water and methylene chloride which is suspected to be a carcinogen. Furthermore, the phosgene process must execute the disposal treatment of large quantities of@wastewater to remove the contaminated organic materials before discharge from the factory. The Asahi Kasei Non-Phosgene Polycarbonate Process enables high-yield production of the two products, high-quality polycarbonate (PC) having excellent properties and high-purity monoethylene glycol (MEG), starting from ethylene oxide (EO), CO2 and bisphenol-A, without waste and wastewater.
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Specificații

ISBN-13: 9781614708773
ISBN-10: 1614708770
Pagini: 315
Ilustrații: Illustrations
Dimensiuni: 186 x 261 x 25 mm
Greutate: 0.86 kg
Editura: Nova Science Publishers Inc

Cuprins

Preface; Chapter 1. Introduction: Society and Chemical Industry; Chapter 2. Background of Polycarbonate; Chapter 3. General Method for Synthesis of Polycarbonate; Chapter 4. Technological Aspects of the Industrial Processes for Producing Aromatic Polycarbonates Using Carbon Monoxide (CO) as a Starting Material; Part 1. Interfacial Polycondensation Phosgene Process; Chapter 5. Technological Aspects of the Industrial Processes for Producing Aromatic Polycarbonates Using Carbon Monoxide (CO) as a Starting Material; Part 2. Non-phosgene Process; Chapter 6. General Aspect of Non-Phosgene Polycarbonate Process from CO2 (Asahi Kasei Process); Chapter 7. Monomer Production Technology from CO2 (Asahi Kasei Process); Chapter 8. Melt Polymerization Technology of Asahi Kasei Process; Chapter 9. Excellent Features of Polycarbonate Produced by Asahi Kasei Non-Phosgene Process; Chapter 10. Economical Features of Asahi Kasei Non-Phosgene Polycarbonate Process; Chapter 11. Contribution of Asahi Kasei Non-Phosgene Polycarbonate Process to Society; Chapter 12. Other Approach 1 Outline of Chemical Fixation of CO2 into Polymer; Chapter 13. Other Approach 2 Development of Non-Phosgene MDI Process; Conclusion; Acknowledgements; Index