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Reaction Mechanisms in Organic Chemistry de M Balci

Reaction Mechanisms in Organic Chemistry

Autor M Balci
en Limba Engleză Hardback – 4 ian 2022
Understanding organic reaction mechanisms is the key for understanding organic chemistry. That is the concept of this unique textbook which supports the students perfectly to understand organic chemistry in a very comprehensive way. Includes a problem & solution section, too.
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Specificații

ISBN-13: 9783527349647
ISBN-10: 3527349642
Pagini: 640
Dimensiuni: 224 x 280 x 36 mm
Greutate: 1.98 kg
Editura: Wiley Vch
Locul publicării:Weinheim, Germany

Cuprins

BASIC CONCEPTS Covalent Bonding and Hybridization Electrophiles and Nucleophiles Inductive and Mesomeric Effects Formal Charge And Oxidation Number Acids And Bases Reaction Kinetics And Energy Diagrams NUCLEOPHILIC SUBSTITUTION REACTIONS Unimolecular Substitution Reactions SN1 Stereochemistry in SN1 Reactions Optical Activity Bimolecular Substitution Reactions SN2 Stereochemistry of SN2 Reactions Nucleophilic Substitution On Allylic Systems: Allylic Rearrangement Internal Nucleophilic Substitution Reaction SNi Neighboring Group Participation in Nucleophilic Substitution Reactions Ambident Nucleophiles Various Nucleophilic Substitution Reactions ELIMINATION REACTIONS Unimolecular Elimination Reactions, E1 Bimolecular Elimination Reactions, E2 Unimolecular Conjugate Base Halogene Elimination Hofmann Elimination: Quaternary Ammonium Salts Pyrolitic Eliminations: Intramolecular cis-Elimination Reactions Elimination at the Bridgehead: Bredt?s Rule ADDITION REACTIONS Halogen Addition To Double Bonds: Halogenation Addition of Hydrogen Halides to Double Bonds: Markovnikov?s Rule Anti-Markovnikov Addition of Hydrogen Halides to Alkenes Addition of Water to Alkenes Oxymercuration and Demercuration Hydroboration of Alkenes: Anti-Markovnikov Hydration Epoxidation of the Alkenes Vicinal cis-Dihydroxylation Dihydroxylation via PIFA Enzymatic Dihydroxylation Ozonolysis: Oxidative Cleavage of Alkenes Reduction of Alkenes Addition to Conjugated Dienes CARBONYL COMPOUNDS AND THEIR REACTIONS Structure-Reactivity Relationships Reactions of Carbonyl Compounds Carbonyl Addition Reactions Umpolung: Polarity Inversion of Aldehyde Carbonyl Group Reactions of Aldehydes and Ketones with Amines Reduction of Carbonyl Groups Reaction of Carbonyl Groups with Organometallic Compounds Reaction of Carbonyl Groups with Ylides Phosphonium Ylides and Wittig Reaction Reactivity of alpha-Carbon Atom Keto-Enol Tautomerism Proton-Deuterium Exchange alpha-Halogenation of Ketones and Aldehydes: Haloform Reaction Hell-Volhard-Zelinsky Reaction alpha-Alkylation of Carbonyl Compounds Enolates Derived from 1,3-Dicarbonyl Compounds Condensation Reactions of Carbonyl Compounds Typical Reactions of Acids and Esters Transesterification AROMATIC COMPOUNDS Structure of Benzene Aromatic, Antiaromatic, and Nonaromatic Compounds Determination of the Molecular orbitals of Aromatic Compounds What are the criteria for aromaticity? How does one quantify aromaticity? Homoaromaticity Möbius Aromaticity Aromatic Ions Annulenes Aromaticity in Fused Systems Aromaticity in Heterocyclic Compounds Electrophilic Aromatic Substitution: Chemistry of Benzene Reactivity of Monosubstituted Benzene Derivatives Directing Effects of Substituents: Activating Groups Electrophilic Aromatic Substitution on Disubstituted Benzenes Functionalization of the Side Chain Substituents of Benzene Nucleophilic Aromatic Substitution Reactions Polycyclic Aromatic Compounds Benzenoid Aromatic Compounds REACTIVE INTERMEDIATES Carbocations Carbanions Carbenes Nitrenes Radicals Singlet Oxygen PERICYCLIC REACTIONS Woodward Hoffmann Rules Frontier Orbitals Electrocyclic Reactions Application of Woodward Hoffmann Rules Correlation Diagrams Cycloaddition Reactions Secondary Orbital Interaction Orbital Coefficients Sigmatropic Reactions Cope and Claisen Rearrangement CARBON-CARBON (C-C) COUPLING REACTIONS History Mizoroki-Heck Coupling Reaction Stille-Coupling Reaction Suzuki-Miyaura Coupling Reaction Negishi-Coupling Reaction Sonogashira-Coupling Reaction Kumada-Coupling Reaction Hiyama-Coupling Reaction Hiyama-Denmark Coupling Buchwald-Hartwig Coupling Tsuji-Trost Coupling Palladium-catalyzed Carbonylation Reactions Carbonylative Coupling Reactions with Organometallic Reagents Mo(CO)6-Mediated Carbonylation