Solution NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models: Current Methods in Inorganic Chemistry, cartea 2
Autor Ivano Bertini, Claudio Luchinat, Giacomo Parigien Limba Engleză Hardback – 3 iul 2001
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Specificații
ISBN-13: 9780444205292
ISBN-10: 0444205292
Pagini: 384
Ilustrații: 1
Dimensiuni: 156 x 234 x 22 mm
Greutate: 0.71 kg
Editura: ELSEVIER SCIENCE
Seria Current Methods in Inorganic Chemistry
ISBN-10: 0444205292
Pagini: 384
Ilustrații: 1
Dimensiuni: 156 x 234 x 22 mm
Greutate: 0.71 kg
Editura: ELSEVIER SCIENCE
Seria Current Methods in Inorganic Chemistry
Cuprins
Selected Contents. Introduction. The hyperfine shift. Relaxation. Chemical exchange, chemical equilibria and dynamics. Transition metal ions: shift and relaxation. Magnetic coupled systems. Nuclear Overhauser effect. Two-dimensional spectra and beyond. Hints on experimental techniques. Appendix I NMR properties of nuclei. Appendix II Dipolar coupling between two spins. Appendix III Derivation of the equations for contact shift and relaxation in a simple case. Appendix IVDerivation of pseudocontact shift in the case of axial symmetry. Appendix V Relaxation by dipolar interaction between two spins. Appendix VI Calculation of (Sz): Curie's law. Appendix VII Derivation of the equations related to NOE. Appendix VIII Magnetically coupled dimers in the high-temperature limit. Appendix IX Product operators: basic tools. Appendix X Reference tables. Subject index.