Strategies for Palladium-Catalyzed Non-directed and Directed C bond H Bond Functionalization
Editat de Anant R. Kapdi, Debabrata Maitien Limba Engleză Paperback – 24 mai 2017
- Addresses the involvement of catalytic systems (palladacycles) for better functionalization of (hetero)arenes to emphasize the need for developing better, more selective systems
- Covers the use of powerful mechanistic tools for understanding and assisting the development of better functionalization strategies
- Discusses the finer aspects of C-H bond functionalization, such as control of regioselectivity with or without directing groups
- Includes a chapter detailing the synthesis of naturally occurring molecules or functional molecules via both pathways for assessing the applicability of the functionalization strategies
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Specificații
ISBN-13: 9780128052549
ISBN-10: 0128052546
Pagini: 500
Dimensiuni: 152 x 229 x 29 mm
Editura: ELSEVIER SCIENCE
ISBN-10: 0128052546
Pagini: 500
Dimensiuni: 152 x 229 x 29 mm
Editura: ELSEVIER SCIENCE
Public țintă
graduate level students, postdocs, and faculty active in transition metal-based catalysisCuprins
1. Introductory chapter on C-H bond functionalization
2. Oxidative Coupling of Aromatic C-H Bonds
3. Directed C-H bond functionalization of heteroarenes
4. Non-directed C-H bond functionalizations of heteroarenes
5. Palladium-Catalyzed Arylation (or Functionalization in general) of Unactivated spz C–H bond
6. C-H bond functionalization at the benzene core of indoles and indolines (excluding C-2 and C-3)
7. Palladium Catalyzed Carbonylative and Carboxylative C-H Functionalization Reactions: Importance and Role of Regioselectivity
8. Flow Chemistry Perspective for C-H Bond Functionalizations
9. Meta selectivity in Directed C-H bond functionalizations
10. Aliphatic distal C-H activation
11. Palladacycles for Directed and Non-Directed C-H bond Functionalization of Heteroarenes
12. Mechanistic Aspect of Directed and Non-Directed C-H Bond Functionalizations
13. Total Synthesis of Natural Products by C-H Activation
2. Oxidative Coupling of Aromatic C-H Bonds
3. Directed C-H bond functionalization of heteroarenes
4. Non-directed C-H bond functionalizations of heteroarenes
5. Palladium-Catalyzed Arylation (or Functionalization in general) of Unactivated spz C–H bond
6. C-H bond functionalization at the benzene core of indoles and indolines (excluding C-2 and C-3)
7. Palladium Catalyzed Carbonylative and Carboxylative C-H Functionalization Reactions: Importance and Role of Regioselectivity
8. Flow Chemistry Perspective for C-H Bond Functionalizations
9. Meta selectivity in Directed C-H bond functionalizations
10. Aliphatic distal C-H activation
11. Palladacycles for Directed and Non-Directed C-H bond Functionalization of Heteroarenes
12. Mechanistic Aspect of Directed and Non-Directed C-H Bond Functionalizations
13. Total Synthesis of Natural Products by C-H Activation