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Supercritical Fluids

Editat de Marcel R. Belinsky
en Limba Engleză Hardback – 31 mar 2010
A supercritical fluid is any substance at a temperature and pressure above its critical point. It can diffuse through solids like a gas, and dissolve materials like a liquid. Additionally, close to the critical point, small changes in pressure or temperature result in large changes in density, allowing many properties to be "tuned". Supercritical fluids are suitable as a substitute for organic solvents in a range of industrial and laboratory processes. Carbon dioxide and water are the most commonly used supercritical fluids, being used for decaffeination and power generation respectively. In general terms, supercritical fluids have properties between those of a gas and a liquid. This new and important book gathers the latest research from around the globe in this field of study with a focus on such topics as: the modification and preparation of membrane in supercritical carbon dioxide, supercritical fluid technology applied to the manufacture of prebiotic carbohydrates, the pre-treatment of herbaceous matrix in a process of supercritical fluid extraction, fundamental properties and chemical reactions of supercritical methanol and others.
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Specificații

ISBN-13: 9781607419303
ISBN-10: 1607419300
Pagini: 790
Ilustrații: tables & charts
Dimensiuni: 186 x 260 x 47 mm
Greutate: 1.59 kg
Ediția:New.
Editura: Nova Science Publishers Inc

Cuprins

Preface; Modification & Preparation of Membrane in Supercritical Carbon Dioxide; The Critical Properties of a Binary Aqueous & CO2 Containing Mixtures & the Krichevskii Parameter; Modeling the Fluid Phase Behavior of Systems Involving High Molecular Weight Compounds & Supercritical Fluids using Cubic & Non-Cubic Equations of State; Supercritical Fluid Technology Applied to the Manufacture of Prebiotic Carbohydrates; Design of Supercritical Fluid Processes for High Molecular Mass Petrochemicals; Considerations for the Design of High-Pressure Phase Equilibrium & Solubility Measurements Equipment; Non-Fluorous, Hydrocarbon-Based, Highly CO2-Soluble Materials; Biodiesel Production: The Problems in Software Design at Supercritical & Subcritical Conditions; Modelling & Analysis of Global Phase Diagrams in CO2 + 1-alkanols Binary Mixtures Using PC--SAFT; Pre-Treatment of Herbaceous Matrix in a Process of Supercritical Fluid Extraction; Heterogeneous Reaction Media using Dense Phase Carbon Dioxide for Catalytic Selective Hydrogenation; Fundamental Properties & Chemical Reactions of Supercritical Methanol; Polymeric Materials Modification with Supercritical CO2 both as Solvent & Swelling Agent; Why is Naphthalene Extensively used for Solubility Comparison?; Supercritical Extraction of Seed Oil: Analysis & Comparison of Up-To-Date Models; Hydrogenation of Terpene in Highly Dense CO2 -- Significance of Phase Equilibria; Stereoselective Hydrogenation of Alkylphenols Over Charcoal-Supported Rhodium Catalyst in Supercritical Carbon Dioxide Solvent; Index.