The Chemistry of Metal Alkoxides de N.Y. Turova

The Chemistry of Metal Alkoxides

N.Y. Turova

Evgeniya P. Turevskaya

Vadim G. Kessler

Maria I. Yanovskaya

This book is devoted to general questions of the chemistry of metal alkoxides – including physiochemical properties, structure, specific features of single groups of alkoxides, theoretical principles of their use, and major applications of this method in the preparation of functional materials.

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Descriere

The study of the chemistry of metal alkoxides, which began more than 100 years ago, is now experiencing a renaissance connected with the broad application of these compounds as molecular precursors in the synthesis of materials of modern technology based on simple and complex oxides. The solution of this problem is occupying a wide circle of inorganic chemists, technologists specializing in fine synthesis in nonaqueous media, and those working on the production of films and coatings. The application of metal alkoxides in the first step of sol-gel technology (based on hydrolysis of alk- ides with subsequent dehydration of the hydrated oxides formed) can benefit from this monograph covering the modern literature devoted to all the steps of this process. The information on chemistry of metal alkoxides has been reported in a number of reviews (devoted to the single groups of derivatives) and numerous original publications. The only other monograph — Metal Alkoxides by D. C. Bradley, R. C. Mehrotra and D. P. Gaur was published in 1978 (A- demic Press, London) and, unfortunately, does not reflect modern findings.

Cuprins

General Synthetic Approaches.- Physicochemical Properties of Alkoxides: Regularities in the Homologous Series.- Crystal and Molecular Structures of Metal Alkoxides.- Oxoalkoxides.- Specific Features of Physico-Chemical Behavior: «Coordination Polymerism».- Heteroleptic Metal Alkoxides Containing Carboxylato-, ?-Diketonato, and Aminoalkoxide Ligands.- Adducts and Heterometallic Alkoxides.- Hydrolysis of Metal Alkoxides and Synthesis of Simple Oxides by The Sol-Gel Method.- Synthesis of Complex Oxides From Metal Alkoxides.- Hybrid Organic-Inorganic Materials.- The Overview of Metal Alkoxide Derivatives along the Groups of the Periodic Table.