Theory and Interpretation of Magnetic Resonance Spectra
Autor W. Dixonen Limba Engleză Paperback – 18 apr 2012
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Specificații
ISBN-13: 9781468478617
ISBN-10: 1468478613
Pagini: 176
Ilustrații: VIII, 164 p.
Dimensiuni: 152 x 229 x 9 mm
Greutate: 0.25 kg
Ediția:Softcover reprint of the original 1st ed. 1972
Editura: Springer Us
Colecția Springer
Locul publicării:New York, NY, United States
ISBN-10: 1468478613
Pagini: 176
Ilustrații: VIII, 164 p.
Dimensiuni: 152 x 229 x 9 mm
Greutate: 0.25 kg
Ediția:Softcover reprint of the original 1st ed. 1972
Editura: Springer Us
Colecția Springer
Locul publicării:New York, NY, United States
Public țintă
ResearchCuprins
1 Introduction and Basic Theory for a Particle in a Field.- 1.1. Introduction.- 1.2. Electostatics and Magnetrostactics.- 1.3. Interactions of Dipoles and Quadrupoles with Fields.- 1.4. Steady Currents and Magnetic Fields.- 1.5. Effects of Changing Fields.- 1.6. The Vector Potential.- 1.7. The Magnetogyric Ratio and Spin.- 2 Elements of Quantum Theory.- 2.1. Hamilton’s Form of Mechanics.- 2.2. Transition to Quantum Mechanics.- 2.3. Commutation Relations.- 2.4. Approximate Methods.- 2.5. The Interaction between Radiation and Matter.- 2.6. Theories of Molecular Structure.- 2.7. Quantum Theory of Spin.- 3 The Observation of Magnetic Resonance.- 3.1. The Resonance Condition.- 3.2. Experimental set-up.- 3.3. Preliminary Look at the Intensity of Absorption.- 3.4. Line Shapes: Classical Introduction.- 3.5. Solution of the Block Equations for Irradiated Samples.- 4 Parameters obtained from Magnetic Resonance Spectra.- 4.1. Introduction.- 4.2. Parameters from Liquid Samples.- 4.3. Some Second-order Effects.- 4.4. Magnetic Resonance in Solid Samples.- 4.5. Magnetic Resonance in the Gas Phase.- 4.6. ESR of Triplet State Molecules.- 5 Theory of Chemical Shifts and g-Values. The Influence of Electronic Orbital Angular Momentum on the Position of Resonance.- 5.1. Expressions for the Magnetic Interactions.- 5.2. g-Values and Chemical Shifts in Atoms.- 5.3. Quenching of Orbital Angular Momentum.- 5.4. The Effects of Spin-Orbit Coupling.- 5.5. The Effective Spin Hamiltonian.- 5.6. Predictions of g-Factors and Chemical Shifts.- 5.7. Further Examples of Chemical Shifts.- 5.8. Proton Chemical Shifts.- 6 The Theory of Coupling Constants.- 6.1. Introduction.- 6.2. Hyperfine Splitting in ESR Spectra.- 6.3. Molecular Orbital Theory of Coupling Constants in Free Radicals.- 6.4. TheValence-Bond Theory of Coupling Constants-Spin Polarization-Negative Spin Density.- 6.5. Anisotropic Coupling Constants in Solids.- 6.6. Nuclear Spin-Spin Coupling in Solution.- 6.7. Valence Bond Theory of Proton Coupling Constants.- 6.8. Molecular Orbital Theories of Coupling Constants.- 7 Time-dependent Effects in Magnetic Resonance.- 7.1. Consequences of Brownian Motion.- 7.2. Nuclear Quadrupole Relaxation.- 7.3. Effects of Changing Environment of a Spin-Interchange Between two Types of Position.- 7.4. Double Resonance.- 7.5. Electron-nuclear Double Resonance.- Further Reading.