Theory of Rate Processes in Condensed Media: Lecture Notes in Chemistry, cartea 20
Autor B. Fainen Limba Engleză Paperback – sep 1980
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Specificații
ISBN-13: 9783540102496
ISBN-10: 3540102493
Pagini: 180
Ilustrații: VI, 168 p.
Dimensiuni: 170 x 244 x 9 mm
Greutate: 0.3 kg
Ediția:Softcover reprint of the original 1st ed. 1980
Editura: Springer Berlin, Heidelberg
Colecția Springer
Seria Lecture Notes in Chemistry
Locul publicării:Berlin, Heidelberg, Germany
ISBN-10: 3540102493
Pagini: 180
Ilustrații: VI, 168 p.
Dimensiuni: 170 x 244 x 9 mm
Greutate: 0.3 kg
Ediția:Softcover reprint of the original 1st ed. 1980
Editura: Springer Berlin, Heidelberg
Colecția Springer
Seria Lecture Notes in Chemistry
Locul publicării:Berlin, Heidelberg, Germany
Public țintă
ResearchCuprins
I Basic Quantum Mechanical Equipment.- 1.1 Basic concepts of quantum theory.- 1.2 Two simple quantum-mechanical systems.- 1.3 Transition probability per unit time. Master equations. General properties of irreversible motion.- 1.4 The Born-Oppenheimer approximation. Phonons. Phonon-phonon interaction and relaxation.- II Basic Processes and Models.- 2.1 Adiabatic and non-adiabatic transitions.- 2.2 Adiabatic transitions. Tunneling..- 2.3 Non-adiabatic transitions. Landau-Zener transition.- 2.4 Electron transfer.- 2.5 Energy transfer.- III The Equation of Motion.- 3.1 Derivation of master equations from von Neumann equation.- 3.2 Equations for density matrix of dynamic subsystem.- 3.3 Master equations for dynamic subsystem.- IV Calculation of Rate Coefficients in Various Temperature Regions.- 4.1 Equation of motion describing electron transfer.- 4.2 Calculation of rate coefficients by the saddle-point method.- 4.3 Integral equation for non-radiative transition rates.- 4.4 Symmetric case of zero energy gap. Temperature dependence.- V Equations of Motion at Zero and Low Temperature Range.- 5.1 Equation of motion in the case when the interaction energy V is not a small parameter.- 5.2 Validity conditions of perturbative approach.- VI Adiabatic Rate Processes.- 6.1 Tunneling in condensed media.- 6.2 Overcoming the potential barrier.- 6.3 General features of adiabatic rate processes.- VII Competition Between Electronic and Vibrational Relaxations.- 7.1 Master equations describing competition between electronic and vibrational relaxations.- 7.2 Master equation approach to non-adiabatic rate processes.- VIII Concluding Remarks.- 8.1 General quantum mechanical analysis.- 8.2 Hierarchy of equations of motion.- 8.3 Models.- References.