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Wave Optics in Infrared Spectroscopy: Theory, Simulation, and Modeling

Autor Thomas G. Mayerhöfer
en Limba Engleză Paperback – 29 mai 2024
Wave Optics in Infrared Spectroscopy starts where conventional books about infrared spectroscopy end. Whereas the latter are based on the Bouguer-Beer-Lambert law, the cornerstones of this book are wave optics and dispersion theory. This gap between both levels of theory is bridged to allow a seamless transition from one to the other. Based on these foundations, the reader is able to choose which level of theory is adequate for the particular problem at hand. Advanced topics like 2D correlation analysis, chemometrics and strong coupling are introduced and viewed from a wave optics perspective. Spectral mixing rules are also considered to better understand spectra of heterogeneous samples. Finally, optical anisotropy is examined to allow a better understanding of spectral features due to orientation and orientational averaging. This discussion is based on a 4 x 4 matrix formalism, which is used not only to simulate and analyze complex materials, but also to understand vibrational circular dichroism from a (semi-) classical point of view. Wave Optics in Infrared Spectroscopy is written as a tool to reunite the fragmented field of infrared spectroscopy. It will appeal to chemists, physicists, and chemical/optical engineers.


  • Assists the reader (including those with less physical science backgrounds) in using more of the extensive benefits that infrared spectroscopy can provide by making them better aware and informed about the higher-level theory
  • Foundations of the book are built on wave optics and dispersion theory versus the Bouguer-Beer-Lambert law of conventional infrared spectroscopy literature
  • Limits of lower level of theory are explained in detail
  • Provides a thorough introduction to more sophisticated topics with a smooth transition from lower to higher-level theory
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Specificații

ISBN-13: 9780443220319
ISBN-10: 044322031X
Pagini: 464
Dimensiuni: 152 x 229 x 24 mm
Greutate: 1.06 kg
Editura: ELSEVIER SCIENCE

Cuprins

Foreword
Isao Noda
Part 1
1. What is wrong with absorbance
2. A simplified calculus
3. The Electromagnetic Field
4. Reflection and transmission of plane waves
5. Dispersion relations
6. Deviations from the (Bouguer-)Beer-Lambert approximation
7. Additional insights gained by wave optics and dispersion theory
8. 2D Correlation Analysis
9. Chemometrics
10. Mixing rules
Part 2
11. What is wrong with linear dichroism theory
12. Reflection and transmission of plane waves from and through anisotropic media – generalized 4×4 matrix formalism
13. Dispersion relations - anisotropic oscillator models
14. Dispersion analysis of anisotropic crystals - examples
15. Polycrystalline materials
16. Vibrational circular dichroism
Bibliography