Asymmetric Catalysis: NATO Science Series E:, cartea 103
Editat de B. Bosnichen Limba Engleză Paperback – 26 sep 2011
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Specificații
ISBN-13: 9789401087919
ISBN-10: 9401087911
Pagini: 172
Ilustrații: 172 p.
Dimensiuni: 155 x 235 x 9 mm
Greutate: 0.25 kg
Ediția:1986
Editura: SPRINGER NETHERLANDS
Colecția Springer
Seria NATO Science Series E:
Locul publicării:Dordrecht, Netherlands
ISBN-10: 9401087911
Pagini: 172
Ilustrații: 172 p.
Dimensiuni: 155 x 235 x 9 mm
Greutate: 0.25 kg
Ediția:1986
Editura: SPRINGER NETHERLANDS
Colecția Springer
Seria NATO Science Series E:
Locul publicării:Dordrecht, Netherlands
Public țintă
ResearchCuprins
1 - General Principles.- 1. Catalysis.- 2. Turnover Limiting Step.- 3. Origin of Catalysis.- 4. Catalytic Cycles.- 5. Classification of Catalysts.- 6. Asymmetric Synthesis.- 7. Asymmetric Discrimination.- 8. Reactant Control and Product Control in the Enantio- selective Step.- References.- 2 - Carbon-Hydrogen Bond Formation.- 1. Asymmetric Catalytic Hydrogenation.- References.- 2. Asymmetric Hydrogenation of Ketones.- References.- 3. Asymmetric Double Bond Migration.- References.- 4. Asymmetric Hydrosilation.- References.- 3 - Carbon-Carbon Bond Formation.- 1. Hydroformylation.- References.- 2. Asymmetric Hydrocarboxylation.- References.- 3. Asymmetric Hydrocyanation.- References.- 4. Asymmetric Allylic Alkylation.- References.- 5. Asymmetric Grignard Cross-Coupling.- References.- 6. Asymmetric Cyclopropanation.- References.- 7. Catalytic Asymmetric Codimerization.- References.- 1. Catalytic Asymmetric Cyclodimerization, Skeletal Rearrangement and Telomerization and Asymmetric [3+2]-Cycloaddition.- References.- 2. Asymmetric Catalyzed Diels-Alder Reaction.- References.- 4 - Asymmetric Oxidation.- 1. Asymmetric Epoxidation.- References.- 2. Asymmetric Oxidation of Sulfides.- References.- 5 - Heterogeneous and Polymer Supported Catalysts.- 1. Impregnated Heterogeneous Catalysts.- 2. Electrochemical Asymmetric Reduction.- References.- 3. Polymer Supported Catalysts.- References.- 6 - Asymmetric Catalysis by Biochemical Systems.- (i) Classification of Enzyme Reactions.- (ii) Coenzymes.- (iii) Fermentative vs. Enzymic Processes.- (iv) Enantiotopic Group Differentiation.- (v) Immobilized Enzymes and Cells.- (vi) Range of Applicability of Enzymes.- References.- 7 - Economic Significance of Asymmetric Catalysis.- 1. Economic Advantages of Asymmetric Synthesis.- 2. Intramolecular Aldol Condensations of Hajos and Eder.- References.- 3. Potential Chirons of Economic Importance.- 4. Examples of Target Molecules which have been more Economically Prepared by Asymmetric Synthesis.- 8 - Future Trends.- 1. Enzymes and Microbes.- 2. Inorganic Systems.- 3. Purely Organic Catalysts.
Recenzii
`... presents an overview of the state of the art of this important subject (as of early 1984). It would be appropriate to any graduate level course in Organometallic, Catalytic, or Synthetic Chemistry. It would also serve as an selective primer for anyone considering serious research in this rapidly expanding field.'
Journal of the American Chemical Society, 108:18 (1986)
Journal of the American Chemical Society, 108:18 (1986)