Chemical & Biochemical Kinetics de Gennady Zaikov

Chemical & Biochemical Kinetics

Gennady Zaikov

en Limba Engleză Paperback – 31 oct 2011

This book examines the new steps of success in the field of chemical and biochemical kinetics. Topics discussed include the activation energy of molecule and atom diffusion in bio-systems; mathematical modelling dependence of thermodynamic characteristics upon spatial-energy parameter of free atoms; dependence of nanostructure formation degree upon spatial-energy characteristics of free atoms; sevilene-based hybrid composites; organosilicon polymers with photo switchable fragments in the side chain and ferrocene-containing polyphenylenes as precursors for magnetic nanomaterials.

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Preface; Activation energy of molecule & atom diffusion in bio-systems; Mathematical modeling dependence of thermodynamic characteristics upon spatial-energy parameter of free atoms; Dependence of nanostructure formation degree upon spatial-energy characteristics of free atoms; Quantum-chemical research of the mechanism of synthesis of 5-acetyloxymethyl-2-chloro-5-ethyl-1,2,3-dioxaphosphorynan; Estimation of acid force of components of synthesis of 5-acetyloxymethyl-2-chloro-5-ethyl-1,2,3-dioxaphosphorynane; Quantum-chemical calculations of electron structure of heme & ion of iron & their reactivity in reactions with hydrogen peroxide; Structure & properties of polymer adsorption layers on inorganic pigments surface in aqueous dispersion formed under ultrasonic treatment; Pigment surface modification in pigment dispersions with thermo-responsive poly(methylvinylether) copolymers in combination with ultrasonic treatment; Properties of carbon-black composite vapor detectors based on multifunctional polymers; Electric conductivity of polymer composites at mechanical relaxation; Organosilicon polymers with photo switchable fragments in the side chain; Moisture permeability & swelling of modified cellulose diacetate films; Ferrocene-containing polyphenylenes as precursors for magnetic nanomaterials; The structure of polybutadienes & butadiene-acrylonitrile copolymers; Relation between the cell-free DNA content & the lipid peroxidation in the blood plasma of mice under damaging action; Inhibition mechanism of natural & synthetic antioxidants in the presence of phospholipids & hydropiroxides; Physicochemical & antimicrobial properties of nanocomposite films based on hydroxyethylcellulose; Sevilene-based hybrid composites -The structure of polybutadienes & butadiene-acrylonitrile copolymers; Effect of chitosan molecular weight on rheological behavior of chitosan modified nanoclay in highly hydrated states; Mechanism of stable radical generation in lignin under the action of nitrogen dioxide; Thermophysical properties of organoplastics based on PA-6; IR-spectra & a crystalline structure of penton & the carboplastic based on it; Template synthesis of bioinorganic polymers on ions of transitive metal; Index.