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Heterogeneous Catalysis Research Progress

Editat de Mathias B. Gunther
en Limba Engleză Hardback – 30 sep 2008
Heterogeneous catalysis is a chemistry term which describes catalysis where the catalyst is in a different phase (ie. solid, liquid and gas, but also oil and water) to the reactants. Heterogeneous catalysts provide a surface for the chemical reaction to take place on. In order for the reaction to occur, one or more of the reactants must diffuse to the catalyst surface and adsorb onto it. After reaction, the products must desorb from the surface and diffuse away from the solid surface. Frequently, this transport of reactants and products from one phase to another plays a dominant role in limiting the reaction rate. Understanding these transport phenomena and surface chemistry such as dispersion is an important area of heterogeneous catalyst research. Catalyst surface area may also be considered. Mesoporous silicates, for example, have found utility as catalysts because their surface areas may be in excess of 1000 m2/g, which increases the probability that a reactant molecule in solution will come in contact with the catalyst surface and adsorb. If diffusion rates are not taken into account, the reaction rates for various reactions on surfaces depend solely on the rate constants and reactant concentrations. Asymmetric heterogeneous catalysis can be used to synthesise enantiomerically pure compounds using chiral heterogeneous catalysts.[1] The field is of great industrial and environmental importance
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Specificații

ISBN-13: 9781604569797
ISBN-10: 1604569794
Pagini: 451
Ilustrații: tables & charts
Dimensiuni: 191 x 261 x 33 mm
Greutate: 1.12 kg
Ediția:New.
Editura: Nova Science Publishers Inc

Cuprins

Preface; Application of Perovskites for Automobile Exhaust Purification; Selective Alkylation of Aromatic Substrates on Spinels; Heterogeneous Fenton Catalysis for the Degradation of Azo Textile Dyes; Reflections on Applied Catalysis and Fundamental Model Studies ; Supported Polyoxometalate-Based Heterogeneous Catalysis for Liquid Phase Selective Oxidations; New Approaches for Reusable Chiral Heterogeneous Catalysts for Epoxide Ring Opening Reaction; Lead-Ruthenate Pyrochlore Modified Nafion Membrane for Tunable Heterogeneous Catalytic Oxidation Reactions; Extracting Information about Surface Heterogeneity Effect on Heterogeneous Reactions using Multifractal Scaling Analysis; Heterogeneous Catalysis Under Continuous Flow Conditions; Index.