Industrial Applications of Homogeneous Catalysis: Catalysis by Metal Complexes, cartea 10
Editat de A. Mortreux, F. Petiten Limba Engleză Hardback – 31 dec 1987
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Specificații
ISBN-13: 9789027725202
ISBN-10: 9027725209
Pagini: 382
Ilustrații: XVII, 360 p.
Dimensiuni: 155 x 235 x 26 mm
Greutate: 0.7 kg
Ediția:1988
Editura: SPRINGER NETHERLANDS
Colecția Springer
Seria Catalysis by Metal Complexes
Locul publicării:Dordrecht, Netherlands
ISBN-10: 9027725209
Pagini: 382
Ilustrații: XVII, 360 p.
Dimensiuni: 155 x 235 x 26 mm
Greutate: 0.7 kg
Ediția:1988
Editura: SPRINGER NETHERLANDS
Colecția Springer
Seria Catalysis by Metal Complexes
Locul publicării:Dordrecht, Netherlands
Public țintă
ResearchCuprins
Chemicals from Methanol and Carbon Monoxide.- 1. Introduction.- 2. Carbonylation of Methanol and of Methanol Derivatives.- 3. Reductive Carbonylation of Methanol and Methanol Derived Substrates.- 4. Oxidative Carbonylation.- 5. Conclusions.- References.- Carbon Monoxide and Fine Chemicals Synthesis.- 1. Basis of Carbon Monoxide Chemistry.- 2. Carbonylation of Organic Halides.- 3. Carbonylation of Alcohols.- 4. Carbonylation of Nitro Compounds.- 5. Carbonylation of Amines.- 6. Carbonylation of Alkenes.- 7. Carbonylation of Alkynes.- 8. Carbonylation of C—H Bonds.- 9. Synthesis of Amino Acids.- 10. Conclusion.- References.- Transition Metal Catalyzed Reductions of Organic Molecules by Molecular Hydrogen and Hydrides: An Overview.- 1. Activation of Molecular Hydrogen.- 2. Some Recent Developments in Hydrogénation: Activation of Hydrides by Transition Metal Derivatives.- 3. Hydrosilylation.- 4. Hydrozirconation.- References.- Application of Transition Metals in Natural Product and Heterocycle Synthesis.- 1. Introduction.- 2. Stoichiometric Reactions: Organocopper Derivatives.- 3. Catalytic Reaction: Palladium and Nickel Organometallic Reagents.- 4. Applications of Palladium and Nickel Complexes in Natural Product Synthesis.- (A) Cross Coupling Reaction of Allyl Halides.- (B) Cross Coupling Reactions of Aromatic Halides.- (C) Cross Coupling Reactions of Aryl Halides with ?-Allyl—Nickel Complexes.- (D) Palladium Catalyzed Cross Coupling Reactions of Organometallics.- (A) Malonates.- (B) Sulfones.- (C) Nitroalkanes.- 5. Particular Applications of Transition Metals.- 6. Applications of Transition Metals in Hydride Chemistry.- 7. Application of Transition Metal Catalysis in Heterocyclic Synthesis (Typical Examples).- 8. Transition Metal-Catalyzed Reactions of Carbenes.-References.- Application of Telomerization and Dimerization to the Synthesis of Fine Chemicals.- 1. Telomerization Reactions.- 2. Dimerization Reactions.- 3. Conclusions.- References.- Oligomerization of Mono olefins.- 1. The Main Catalysts for Oligomerization.- 2. Mechanistic Considerations.- 3. Heterogeneous and Supported Catalysts.- 4. Industrial Developments.- References.- Coordination Polymerization of Monoolefins and Diolefins.- 1. Introduction: The Discovery.- 2. Polymerization of Monoolefins.- 3. Polymerization of Diolefins.- 4. Homo- and Copolymerization or Other Types of Monomers.- 5. General Conclusions.- References.- Olefin Metathesis and Related Reactions.- 1. Introduction.- 2. Scope of the Reaction.- 3. Catalysts.- 4. Mechanism of the Reaction.- 5. Stereoselectivities.- 6. Initial Production of Carbene.- 7. Metallacarbenes as Catalyst.- 8. Role of Oxygen.- 9. Industrial Applications.- 10. Conclusion.- References.- Activation of Alkane CH Bonds by Orga-nometallics.- 1. Introduction.- 2. Oxidative Addition of Alkane CH Bonds to Organometallics.- 3. Activation of Alkanes by Organoactinides.- 4. Conclusions.- References.- Coordination Photochemistry: Photoinduced Electron Transfer and Redox Photocatalysis.- 1. Introduction.- 2. Properties of the Excited State.- 3. Examples of Coordination Compounds with Charge Transfer Transitions.- 4. Electron Transfer Reaction of the Excited State.- 5. Photochemical Conversion and Storage of Light Energy.- 6. Concluding Remarks.- An Introduction to the Field of Catalysis by Molecular Clusters and by Supported Molecular Clusters and Complexes.- 1. An Introduction to Molecular Clusters.- 2. Catalysis by Molecular Clusters.- References.- Future Trends in Homogeneous Catalysis.- 1. Industrial Applications of Homogeneous Catalysis.- 2. Advantages and Disadvantages of Homogeneous Catalysis.- 3. Future Applications of Homogeneous Catalysis.- References.- Index 349.
Recenzii
`This is a useful addition to the literature, and is of considerably better value than many books arising from conferences and courses.'
`The editors have produced an attractive book ...'
Journal of Organometallic Chemistry, 350, 1988
`I would certainly recommend this book for purchase in libraries. Industrial and academic research groups concerned with the applications of transition metals as organic reagents and catalysts might well wish to have copies close at hand.'
Journal of Electroanalysis Chemistry, 1988
`The editors have produced an attractive book ...'
Journal of Organometallic Chemistry, 350, 1988
`I would certainly recommend this book for purchase in libraries. Industrial and academic research groups concerned with the applications of transition metals as organic reagents and catalysts might well wish to have copies close at hand.'
Journal of Electroanalysis Chemistry, 1988