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Light and Matter Id / Licht und Materie Id: Infrared and Raman Spectra of Non-Metals: Handbuch der Physik Encyclopedia of Physics, cartea 5 / 25 / 2 / 2d

Autor H. Bilz Editat de L. Genzel Autor D. Strauch, R. K. Wehner
en Limba Engleză Paperback – 10 mar 2012
The dynamical properties of solids have recently attracted renewed interest in connection with the increasing understanding of phase transitions and re­ lated phenomena. In particular, soft modes or, more generally, phonon 'anom­ alies' seem to play an important role in structural and electronic phase tran­ sitions, such as ferroelectric or superconducting transitions. The understanding of the mechanisms responsible for the occurrence of unusually low frequencies in phonon spectra requires a detailed analysis of the microscopic forces governing the lattice vibrations. Of particular importance is the influence of the electron­ lattice interaction in the adiabatic approximation which in many cases is the origin of peculiarities in the phonon self-energy. In this work the vibrational spectra of pure non-metals and of those con­ taining point defects are investigated. ' In these materials the interrelation be­ tween the pseudo-harmonic forces (determining the phonon dispersion re­ lations) and the non-linear anharmonic and electron-phonon forces (as they act in infrared and Raman spectra) is most obvious and can be quantitatively analysed in terms of appropriate models. The main task is to arrive at a physically correct treatment of electronic degrees of freedom, as for example in an electronic 'shell' model, which leads to the description of phonon spectra in terms of long-range polarizabilities and short-range deformabilities. The pur­ pose of our review is to stimulate further investigations which, we hope, will result in explicit relations between the parameters of the semi-microscopic models and the matrix elements from the electronic band structure.
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Specificații

ISBN-13: 9783642464355
ISBN-10: 3642464351
Pagini: 620
Ilustrații: XIV, 602 p.
Dimensiuni: 170 x 244 x 33 mm
Greutate: 0.97 kg
Ediția:Softcover reprint of the original 1st ed. 1984
Editura: Springer Berlin, Heidelberg
Colecția Springer
Seriile Handbuch der Physik Encyclopedia of Physics, Optik / Optics

Locul publicării:Berlin, Heidelberg, Germany

Public țintă

Research

Cuprins

Vibrational Infrared and Raman Spectra of Non-Metals.- A. Introduction.- B. Phonons in insulators.- C. Interaction of photons with matter.- D. Expansion theory of susceptibilities and polarizabilities.- E. Interpretation of experimental spectra.- F. Lattices with point defects.- G. Dynamical theory of interacting phonon systems.- H. Appendices.