Liquid-Liquid InterfacesTheory and Methods de Alexander G. Volkov

Liquid-Liquid InterfacesTheory and Methods

Alexander G. Volkov

David W. Deamer

Update your knowledge of the chemical, biological, and physical properties of liquid-liquid interfaces with Liquid-Liquid Interfaces: Theory and Methods. This valuable reference presents a broadly based account of current research in liquid-liquid interfaces and is ideal for researchers, teachers, and students. Internationally recognized investigators of electrochemical, biological, and photochemical effects in interfacial phenomena share their own research results and extensively review the results of others working in their area.
Because of its unusually wide breadth, this book has something for everyone interested in liquid-liquid interfaces. Topics include interfacial and phase transfer catalysis, electrochemistry and colloidal chemistry, ion and electron transport processes, molecular dynamics, electroanalysis, liquid membranes, emulsions, pharmacology, and artificial photosynthesis. Enlightening discussions explore biotechnological applications, such as drug delivery, separation and purification of nuclear waste, catalysis, mineral extraction processes, and the manufacturing of biosensors and ion-selective electrodes.
Liquid-Liquid Interfaces: Theory and Methods is a well-written, informative, one-stop resource that will save you time and energy in your search for the latest information on liquid-liquid interfaces.

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Cuprins

1. Equilibrium electric potential between two immiscible electrolyte solutions /T. Kakiuchi -- I. Distribution potential -- A. Phase-boundary potential -- B. Distribution potential at ITIES -- 1. Nernst equation -- 2. Standard ion transfer potential -- 3. Calculation of distribution potential -- 4. Distribution potential in the presence of ion pair formation and complex formation reactions -- 5. Distribution of potential -- 6. Distribution potential in small systems -- II. Polarizability of the liquid-liquid interface -- III. Nonpolarized ITIES and reference potentials in organic phases -- IV. Free energy of coupling of ion transfer and electron transfer -- 1. Mixed potential determined by electron transfer and ion transfer at ITIES -- 2. Partition of indifferent electrolyte ions -- 3. Relative strength of ion transfer and electron transfer -- V. Conclusions -- VI. References -- 2. Volta and surface potentials at liquid /liquid interfaces /Z. Koczorowski -- I. Introduction -- II. Electrified liquid /liquid interfaces and their electrical potentials -- III. Volta potential and voltaic cells -- IV. Voltaic cells with water /nonpolar liquid interfaces -- V. Voltaic cells with immiscible electrolyte solution interface -- VI. Experimental methods of investigation of voltaic cells -- VII. Final remarks -- VIII. References -- 3. Ion solvation /Y. Marcus -- I. Introduction -- II. The relevant properties of ions -- III. The relevant properties of solvents -- IV. Quantities describing ionic hydration -- A. Thermodynamics of ion hydration -- B. Methods of investigation -- C. Other properties relevant to ion hydration -- D. The data -- E. Interpretation -- V. Transfer of ions into non-aqueous solvents -- A. Methods of investigation -- B. The data -- C. Interpretation -- VI. Preferential ion solvation in mixed solvents -- VII. References -- 4. Adsorption isotherms and the structure of oil /water interface /V. S. Markin and A. G. Volkov -- I. Introduction -- II. Surface solution