Organic Syntheses by Oxidation with Metal Compounds
Editat de W.J. Mijs, C.R.H.I. de Jongeen Limba Engleză Paperback – 31 ian 1987
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Specificații
ISBN-13: 9780306419997
ISBN-10: 0306419998
Pagini: 908
Ilustrații: XXVIII, 908 p.
Dimensiuni: 178 x 254 x 47 mm
Greutate: 1.6 kg
Ediția:1986
Editura: Springer Us
Colecția Springer
Locul publicării:New York, NY, United States
ISBN-10: 0306419998
Pagini: 908
Ilustrații: XXVIII, 908 p.
Dimensiuni: 178 x 254 x 47 mm
Greutate: 1.6 kg
Ediția:1986
Editura: Springer Us
Colecția Springer
Locul publicării:New York, NY, United States
Public țintă
ResearchCuprins
1. Oxidation by Vanadium Compounds.- 1. Introduction.- 2. Mechanisms.- 3.Scope and Limitations.- 4.Experimental Considerations and Procedures.- References.- 2. Oxidation by Oxochromium(VI) Compounds.- 1. Introduction.- 2. Mechanisms.- 3.Scope and Limitations.- 4.Experimental Considerations and Procedures.- References.- 3. The Oxidation of Organic Compounds by Active Manganese Dioxide.- 1.Introduction.- 2.Mechanism.- 3.Oxidation of Alcohols and Hydroxy Compounds.- 4.Dehydrogenation and Oxidative Aromatization.- 5.Hydrocarbons.- 6.Amines and Hydrazines.- 7.Miscellaneous Oxidations.- 8.Experimental Procedures.- References.- 4. Reactions with Manganese(III) Acetate.- 1. Introduction.- 2. Synthesis and Properties of Manganese (III) Acetate.- 3. Oxidative Addition Reactions of Acids to Olefinic Unsaturated Systems.- 4. Mn(III) Acetate-Initiated Addition of Aldehydes to Olefinic Unsaturated Systems.- 5. Mn(III) Acetate-Initiated Addition of Ketones to Olefinic Unsaturated Systems.- 6. Mn(III) Acetate-Acetone - Initiated Addition of Haloalkanes to Unsaturated Systems.- 7. Aromatic Substitution Reactions.- 8. Direct Oxidation Reactions with Manganese (III) Acetate.- 9. Synthetic Procedures.- References.- 5. Oxidations by Cobalt Compounds.- 1. Introduction.- 2. Mechanisms.- 3. Scope and Limitations.- 4. Experimental Considerations and Procedures.- References.- 6. Oxidation of Organic Compounds with Nickel Peroxide.- 1. Introduction.- 2. Mechanism of Oxidation.- 3. Scope and Limitations.- 4. Experimental Considerations.- References.- 7. Oxidations of Organic Compounds Catalyzed by Copper- and Cobalt-Amine Complexes.- 1. Introduction.- 2. Mechanism.- 3. Scope and Limitations.- 4. Experimental Considerations and Procedures.- 5. Tabular Survey of Oxidations of Organic Compounds Catalyzed by Copper- and Cobalt-Amine Complexes.- References.- 8. Ruthenium Tetroxide Oxidations.- 1. Introduction.- 2. The Mechanism of Ruthenium Tetroxide Oxidations.- 3. Scope and Limitations.- 4. Experimental Considerations and Procedures.- References.- 9. Oxidations Using Palladium Compounds.- 1. Introduction.- 2. Oxidation of Olefins.- 3. Vinylic Substitution Reactions.- 4. Aromatic Substitution Reactions.- 5. Oxidative Carbonylations.- 6. Some Reactions of Alcohols.- 7. Examples.- References.- 10. Silver Carbonate on Celite Oxidations.- 1. Introduction.- 2. Mechanism.- 3. Scope and Limitations.- 4. Experimental Procedures.- References.- 11. Cerium(IV) Oxidation of Organic Compounds.- 1. Introduction.- 2. Mechanism.- 3. Scope and Limitations.- Note Added in Proof.- 4. Experimental Conditions and Procedures.- 5. Tabular Survey of Oxidation Reactions.- References.- 12. Oxidations of Organic Compounds with Osmium Tetroxide.- 1. Introduction.- 2. General Mechanism of Osmium Tetroxide Oxidation Reactions.- 3. Scope and Limitations.- 4. Experimental Considerations and Procedures.- References.- 13. Thallium(IH) Salts as Oxidants in Organic Synthesis.- 1. Introduction.- 2. Scope and Limitations.- 3. Experimental Considerations and Procedures.- References.- 14. Oxidations with Lead Tetraacetate.- 1. Introduction.- 2. Hydrocarbons.- 3. Monohydroxylic Alcohols.- 4. 1,2-Diols and Polyols.- 5. Phenols.- 6. Carbonyl Compounds.- 7. Carboxylic Acids.- 8. Nitrogen-Containing Compounds.- 9. Experimental Considerations and Procedures.- 10. Addendum.- References.- 15. Bismuth-Salt Oxidations.- 1. Introduction.- 2. Sodium Bismuthate Oxidations.- 3. Bismuth Trioxide Oxidations.- 4. Organobismuth Reagents.- 5.The Toxicity of Bismuth.- References.- 16. Oxidations with Metal Compounds and Peroxides.- 1. Introduction.- 2. Mechanism.- 3. Scope and Limitations.- 4. Experimental Considerations and Procedures.- References.