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Silane Coupling Agents

Autor E.P. Plueddemann
en Limba Engleză Paperback – 4 iun 2013
* Much progress has been made in the last 8 years in understanding the theory and practice of silane coupling agents. A major advance in this direction was the measurement of true equilibrium constants for the hydroly­ sis and formation of siloxane bonds. Equilibrium constants for bond reten­ tion are so favorable that a silane coupling agent on silica has a thousandfold advantage for bond retention in the presence of water over an alkoxysilane bond formed from hydroxy-functional polymers and silica. In practice, the bonds of certain epoxies to silane-primed glass resist debonding by water about a thousand times as long as the epoxy bond to unprimed glass. Oxane bonds of silane coupling agents to metal oxides seem to follow the same mechanism of equilibrium hydrolysis and rebonding, although equilibrium constants have not been measured for individual metal-oxygen­ silicon bonds. This suggests, however, that methods of improving bond retention to glass will also improve the water resistance of bonds to metals. of standard coupling agents with a hydrophobic silane or one Modification with extra siloxane cross-linking have improved the water resistance of bonds to glass and metals another hundredfold over that obtained with single coupling agents.
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Specificații

ISBN-13: 9781489920720
ISBN-10: 1489920722
Pagini: 272
Ilustrații: XIII, 253 p.
Dimensiuni: 155 x 235 x 14 mm
Greutate: 0.39 kg
Ediția:2nd ed. 1991. Softcover reprint of the original 2nd ed. 1991
Editura: Springer Us
Colecția Springer
Locul publicării:New York, NY, United States

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Research

Cuprins

1. General Concepts.- 2. Chemistry of Silane Coupling Agents.- 3. Aqueous Solutions of Silane Coupling Agents.- 4. Surface Chemistry of Silanes at the Interface.- 5. Nature of Adhesion Through Silane Coupling Agents.- 6. Performance of Silane Coupling Agents.- 7. Particulate-Filled Composites.- 8. Other Applications of Silane Coupling Agents.