The Chemical Equilibrium of Gaseous Systems
Autor R. Holub, P. Vonkaen Limba Engleză Hardback – 31 dec 1975
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Specificații
ISBN-13: 9789027705563
ISBN-10: 9027705569
Pagini: 280
Ilustrații: IV, 279 p.
Dimensiuni: 156 x 234 x 21 mm
Greutate: 0.58 kg
Ediția:1976
Editura: SPRINGER NETHERLANDS
Colecția Springer
Locul publicării:Dordrecht, Netherlands
ISBN-10: 9027705569
Pagini: 280
Ilustrații: IV, 279 p.
Dimensiuni: 156 x 234 x 21 mm
Greutate: 0.58 kg
Ediția:1976
Editura: SPRINGER NETHERLANDS
Colecția Springer
Locul publicării:Dordrecht, Netherlands
Public țintă
ResearchCuprins
List of contents.- 1 Introduction.- 2 Stoichiometry of Chemical Reactions.- 2.1 Definition of a chemical reaction.- 2.2 Determination of the number of linearly independent reactions.- 2.3 Calculation of the matrix of stoichiometric coefficients.- 2.4 Expression of the mass balance.- 3 Chemical Equilibrium of a System.- 3.1 General considerations.- 3.2 The equilibrium constant and ?G° of a reaction.- 3.3 Selection of the standard state.- 3.4 Dependence of the equilibrium constant on variables of state.- 3.5 Dependence of the equilibrium constant on the absolute magnitude of the stoichiometric coefficients.- 3.6 Properties of the free enthalpy of a system.- 3.7 Procedure of calculating a chemical equilibrium.- 4 Chemical Equilibrium of Simple Systems in the Ideal Gas State.- 4.1 Reaction coordinate.- 4.2 Calculation of simple equilibria.- 4.3 Dependence of the degree of conversion on individual reaction conditions.- 4.4 Dependence of the equilibrium composition on individual reaction variables in the case of more complicated systems.- 5 Chemical Equilibrium of Complex System in the Ideal Gas State.- 5.1 Introduction.- 5.2 Single-purpose procedures.- 5.3 General methods requiring stoichiometric analysis of the system.- 5.4 General methods which do not require stoichiometric analysis of the system.- 5.5 Evaluation.- 5.6 Description of selected methods.- 5.7 Calculation of the enthalpy balance of complicated systems.- 6 Chemical Equilibria in Real Gas Systems.- 6.1 Fundamentals thermodynamic notions.- 6.2 Determination of equilibrium composition.- 6.3 Determination of the fugacity coefficients of constituents in the system.- 6.4 Determination of the constants of equations of state of pure constituents.- 7 Practical Calculation Procedure.- 7.1 Source of thermochemicaldata.- 7.2 Strategy of calculation.- 7.3 Processing the calculated results.- 7.4 Example.- Appendix 1 Solution of one non-linear equation.- Appendix 2 Solution of a set of non-linear equations.- Appendix 3 Proof of the inequality.- Appendix 4 Proof of the asymptotic relationship.- Appendix 5 Maximum yield of a reaction.- Appendix 6 Proof of the existence and unambiguous nature of the solution to the problem of chemical equilibrium in ideal gas systems.- Appendix 7 Values of the most frequently encountered compounds in the range of 298.15 to 1200 K, and values of in cal mole and cal mole resp..- Appendix 9 Critical data of selected organic substances.- Appendix 10 Values of constants of the Beattie-Bridgman equation.- Appendix 11 Values of constants of the Benedict-Webb-Rubin equation.- References.