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Theoretical Aspects of Band Structures and Electronic Properties of Pseudo-One-Dimensional Solids: Physics and Chemistry of Materials with B, cartea 4

Editat de Hitomi Kimura
en Limba Engleză Hardback – 31 oct 1985
This volume presents a sequence of articles which describe the theoretical treat­ ments of investigating the fundamental features in the electronic structures and properties of typical quasi-one-dimensional solids; organic conductor TTF-TCNQ, polyacetylene, metallic and superconducting polymer (SN)n and linear chain chal­ cogenides and halides of transition elements including NbSe3' The aim of this volume is not to present an exhaustive review but rather to touch on a selective class of problems which appear to be fundamental for typical quasi-one-dimensional solids. Thus the topics in this volume are rather confined to the key basic properties of quasi-one-dimensional systems. The quasi-one-dimensional solids are one of the most extensively investigated subjects in current physics, chemistry and materials science. These materials are unique in attracting a broad range of scientists, chemists, experimental and theore­ tical physicists, materials scientists and engineers. In 1954 Frohlich constructed a theory of superconductivity based on a one-dimensional model of moving charge density waves. In 1955 Peierls predicted that anyone-dimensional metal is unstable against the distortion of a periodic lattice so that a metal-nonmetal transition occurs at a certain temperature for a one-dimensional metal. According to these theories a gap is opened at the Fermi surfaces of one-dimensional conductors at low tempera­ tures and the charge density wave is created in connection with the occurrence of the gap.
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Specificații

ISBN-13: 9789027719270
ISBN-10: 9027719276
Pagini: 296
Ilustrații: XI, 284 p.
Dimensiuni: 210 x 297 x 22 mm
Greutate: 0.63 kg
Ediția:1985
Editura: SPRINGER NETHERLANDS
Colecția Springer
Seria Physics and Chemistry of Materials with B

Locul publicării:Dordrecht, Netherlands

Public țintă

Research

Cuprins

Theoretical Aspects of Conducting Polymers: Electronic Structure and Defect States.- 1. Introduction.- 2. Ground State Configuration (Hückel Theory).- 3. The Continuum Limit.- 4. Intrinsic Defects.- 5. Towards a More Realistic Theory of Conducting Polymers.- 6. Concluding Remarks.- Appendix A: Local Bond Order and Local Density in the Peierls Distorted State.- Appendix B: Polaron—Type Solutions.- Appendix C: Acoustic Phonons.- References.- Equilibrium Properties of TTF-TCNQ.- 1. Introduction.- 2. Interaction Scheme.- 3. Coulomb Correlated Electron Gas.- 4. CDW Coupling to the Lattice.- 5. Three-Dimensional Ordering.- References.- Band Structures and Electronic Properties of Metallic Polymer (SN)x and Its Intercalates (SNBry)x.- 1. Introduction.- 2. Self-Consistent Numerical Basis Set LCAO Method.- 3. Band Structure and Fermi Surface of (SN)x.- 4. Optical Absorption Spectra of (SN)x.- 5. Fermi Surfaces and Optical Absorption Spectra of (SNBry)x.- 6. Electrical Resistivity in an Interacting Two-Carrier System.- 7. Electrical Resistivity of (SN)x and (SNBry)x.- 8. Summary.- References.- The Quasi-One-Dimensional Chalcogenides and Halides of Transition Elements.- 1. Introduction.- 2. Metal—Metal Pairing in NbI4.- 3. Transition Metal Trichalcogenides.- 4. Zirconium and Hafnium Pentatellurides.- 5. Other One-Dimensional Compounds.- References.- Electronic Structure of NbSe3.- 1. Low-Dimensional Material NbSe3.- 2. Methodology of a Band Calculation.- 3. Results of the Band Calculation.- 4. Discussion.- References.- Index of Names.- Index of Subjects.