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17 0 NMR Spectroscopy in Organic Chemistry

Autor David W. Boykin
en Limba Engleză Hardback – 20 noi 1990
This book provides a comprehensive review of the application of 17O NMR spectroscopy to organic chemistry. Topics include the theoretical aspects of chemical shift, quadrupolar and J coupling; 17O enrichment; the effect of steric interactions on 17O chemical shifts of functional groups in flexible and rigid systems; the application of 17O NMR spectroscopy to hydrogen bonding investigations; mechanistic problems in organic and bioorganic chemistry; and 17O NMR spectroscopy of oxygen monocoordinated to carbon in alcohols, ethers, and derivatives. Recent results that show correlations between molecular geometry, determined by X-ray studies and estimated by molecular mechanics calculations, and 17O chemical shifts are also covered. 17O Spectroscopy in Organic Chemistry provides important reference information for organic chemists and other scientists interested in 17O NMR spectroscopy as a tool for obtaining new structural and chemical data about organic molecules.
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Specificații

ISBN-13: 9780849348679
ISBN-10: 0849348676
Pagini: 332
Ilustrații: 120 Tables, black and white
Dimensiuni: 178 x 254 x 19 mm
Greutate: 0.79 kg
Ediția:1
Editura: CRC Press
Colecția CRC Press

Public țintă

Professional

Cuprins

1. The NMR Parameters for Oxygen-17 2. 17O Enrichment Methods 3. Applications of 17O NMR Spectroscopy to Structural Problems in Organic Chemistry: Torsion Angle Relationships 4. Applications of 17O NMR Spectroscopy to Structural Problems in Rigid, Planar Organic Molecules 5. 17O NMR Spectroscopy: Hydrogen-Bonding Effects 6. 17O NMR as a Mechanistic Probe to Investigate Chemical and Bioorganic Problems 7. 17O NMR Spectroscopy of Single Bonded Oxygen: Alcohols, Ethers, and Their Derivatives 8. 17O NMR Spectroscopic Data for Carbonyl Compounds: I. Aldehydes and Ketones II.Carboxylic Acids and Derivatives 9. I. Oxygen Bound to Nitrogen II. Oxygen Bound to Oxygen 10. Oxygen-17 Nuclear Magnetic Resonance (NMR) Spectroscopy of Organosulfur and Organophosphorus Compounds

Descriere

This book covers a large range of applications of 170 NMR spectroscopy to organic chemistry. It describes theoretical aspects of chemical shift, quadrupolar and J coupling and methods for 17O enrichment.