Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels: Springer Theses
Autor Wenyu Sunen Limba Engleză Hardback – 22 aug 2023
On the basis of experimental measurements and model interpretations, this work highlighted two important combustion characteristics regarding the practical use: the pollutant formation and the ignition performance. Besides, the correlation between oxygen-containing functional groups and the aforementioned combustion characteristics was revealed. To reveal the potential interactions between the reaction networks of oxygenated additives and the hydrocarbon base fuels during combustion. Chemical structures of laminar premixed flames fueled by binary fuels were measured, and by changing the initial fuel compositions, the addition effects of the oxygenates on the fuel consumption and pollutant formation behaviors were explored. It was found that complicated chemical interactions do not exist in the reaction networks under the investigated conditions.
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Specificații
ISBN-13: 9789819945092
ISBN-10: 9819945097
Pagini: 168
Ilustrații: XV, 168 p. 141 illus., 100 illus. in color.
Dimensiuni: 155 x 235 mm
Greutate: 0.5 kg
Ediția:1st ed. 2023
Editura: Springer Nature Singapore
Colecția Springer
Seria Springer Theses
Locul publicării:Singapore, Singapore
ISBN-10: 9819945097
Pagini: 168
Ilustrații: XV, 168 p. 141 illus., 100 illus. in color.
Dimensiuni: 155 x 235 mm
Greutate: 0.5 kg
Ediția:1st ed. 2023
Editura: Springer Nature Singapore
Colecția Springer
Seria Springer Theses
Locul publicării:Singapore, Singapore
Cuprins
Introduction.- Experimental and kinetic modeling methods.- High-temperature kinetics of carbonate and ketone fuels.- Low-temperature oxidation kinetics of polyether fuels.- Addition effects of oxygenated fuels on hydrocarbon premixed flames.- Conclusions and perspective.
Notă biografică
Dr. Wenyu Sun received his B.E. degree from Huazhong University of Science and Technology, Hubei , China, in 2013 and the Ph.D. degree in Engineering from Tsinghua University, Beijing, China, in 2018. Dr. Sun received Bernard Lewis Fellowship from International Combustion Institute, 2018. His Ph.D.thesis was nominated as The Excellent Ph.D. Thesis of Tsinghua University in 2018.
Dr. Sun's work work is centered on combustion kinetics of oxygenated fuels by using experimental, kinetic modeling and theoretical methods. He has published more than 20 scientific papers since 2017. He also serves as reviewer for the journals Proceedings of the Combustion Institute, Combustion Science and Technology since 2017.
Textul de pe ultima copertă
In this thesis, attention was paid to several novel oxygenated fuels—carbonates, polyethers and ketones. Combustion kinetic investigations were performed for typical representative compounds, including dimethyl carbonate, diethyl carbonate, cyclopentanone, 3-pentanone, 1,2-dimethoxyethane and dimethoxymethane. For experiments, suitable diagnostic techniques were used to measure the detailed speciation information of the target fuels under different conditions. For kinetic modeling, rate coefficients for crucial elementary reactions were obtained through high-level theoretical calculations. Based on that, validated kinetic models with good predictive performances were developed.
On the basis of experimental measurements and model interpretations, this work highlighted two important combustion characteristics regarding the practical use: the pollutant formation and the ignition performance. Besides, the correlation between oxygen-containing functional groups and the aforementioned combustion characteristics was revealed. To reveal the potential interactions between the reaction networks of oxygenated additives and the hydrocarbon base fuels during combustion. Chemical structures of laminar premixed flames fueled by binary fuels were measured, and by changing the initial fuel compositions, the addition effects of the oxygenates on the fuel consumption and pollutant formation behaviors were explored. It was found that complicated chemical interactions do not exist in the reaction networks under the investigated conditions.
Caracteristici
The author received a “Bernard Lewis” Fellowship from the Combustion Institute Nominated by Tsinghua University as an outstanding Ph.D. thesis Reveals the correlations between fuel structure features between combustion properties such as emission formation