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Lithium Intercalation in Bilayer Graphene Devices: Springer Theses

Autor Matthias Kühne
en Limba Engleză Hardback – 10 dec 2018
This book reports on the successful implementation of an innovative, miniaturized galvanic cell that offers unprecedented control over and access to ionic transport. It represents a milestone in fundamental studies on the diffusive transport of lithium ions between two atomically thin layers of carbon (graphene), a highly relevant aspect in electrodes for energy and mass storage in the context of batteries. Further, it is a beautiful example of how interdisciplinary work that combines expertise from two very distinct fields can significantly advance science. Machinery and tools common in the study of low-dimensional systems in condensed matter physics are combined with methods routinely employed in electrochemistry to enable truly unique and powerful experiments. 
The method developed here can easily be generalized and extended to other layered materials as well as other ionic species. Not only the method but also the outcome of its application to Li diffusion and intercalation in bilayer graphene is remarkable. A record chemical diffusion coefficient is demonstrated, exceeding even the diffusion of sodium chloride in water and surpassing any reported value of ion diffusion in single-phase mixed conducting materials. This finding may be indicative of the exceptional properties yet to be discovered in nanoscale derivatives of bulk insertion compounds.


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Specificații

ISBN-13: 9783030023652
ISBN-10: 3030023656
Pagini: 140
Ilustrații: XVI, 116 p. 64 illus., 60 illus. in color.
Dimensiuni: 155 x 235 mm
Greutate: 0.37 kg
Ediția:1st ed. 2018
Editura: Springer International Publishing
Colecția Springer
Seria Springer Theses

Locul publicării:Cham, Switzerland

Cuprins

Introduction.- Electronic Properties.- Electrochemical Device Setup and Fabrication.- Lithiation Studies.- Conductivity Corrections from Quantum Interferences.- Intercalate Diffusion Pathways.- Intercalate Diffusion Kinetics.- Summary.

Textul de pe ultima copertă

This book reports on the successful implementation of an innovative, miniaturized galvanic cell that offers unprecedented control over and access to ionic transport. It represents a milestone in fundamental studies on the diffusive transport of lithium ions between two atomically thin layers of carbon (graphene), a highly relevant aspect in electrodes for energy and mass storage in the context of batteries. Further, it is a beautiful example of how interdisciplinary work that combines expertise from two very distinct fields can significantly advance science. Machinery and tools common in the study of low-dimensional systems in condensed matter physics are combined with methods routinely employed in electrochemistry to enable truly unique and powerful experiments. 
The method developed here can easily be generalized and extended to other layered materials as well as other ionic species. Not only the method but also the outcome of its application to Li diffusion and intercalation in bilayer graphene is remarkable. A record chemical diffusion coefficient is demonstrated, exceeding even the diffusion of sodium chloride in water and surpassing any reported value of ion diffusion in single-phase mixed conducting materials. This finding may be indicative of the exceptional properties yet to be discovered in nanoscale derivatives of bulk insertion compounds.




Caracteristici

Nominated as an outstanding PhD thesis by the Max Planck Institute for Solid State Research, Germany Proposes an innovative and versatile on-chip electrochemical cell architecture Offers initial yet comprehensive insights into intercalation chemistry, investigated in the most fundamental unit of a host compound Introduces a novel approach to probing intercalate diffusion kinetics