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Studies on Green Synthetic Reactions Based on Formic Acid from Biomass: Springer Theses

Autor Ming-Chen Fu
en Limba Engleză Paperback – 12 aug 2021
This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized α, β- and β, γ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry. 
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Specificații

ISBN-13: 9789811576256
ISBN-10: 9811576254
Ilustrații: XIV, 105 p. 189 illus., 24 illus. in color.
Dimensiuni: 155 x 235 mm
Greutate: 0.18 kg
Ediția:1st ed. 2020
Editura: Springer Nature Singapore
Colecția Springer
Seria Springer Theses

Locul publicării:Singapore, Singapore

Cuprins

Introduction.- Conversion of Formic Acid as C1 building block on Organic Synthesis.- Non-Metal Boron-Catalyzed N-methylation Conversion of Amines with Formic Acid.- Nickel-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid through Catalytic CO Recycling.- Efficient Pd-Catalyzed Carboxylation of Allylic Alcohols with Formic Acid.- Conclusions.

Notă biografică

Dr. Ming-Chen Fu received his B.Sc. degree from Hefei University of Technology in 2013, and doctoral degree from The University of Science and Technology of China (USTC) under the supervision of Prof. Yao Fu in 2018. He then worked as a postdoctoral fellow at USTC. His research interests are focused on green synthetic reactions based on formic acid, and development of novel catalytic systems in visible light-induced decarboxylative coupling reactions.

Textul de pe ultima copertă

This book introduces readers to the use of formic acid for efficient organic synthesis. It describes the N-methylation of aromatic and aliphatic amines with formic acid using a boron-based catalyst [B(C6F5)3] in combination with silanes and without the need for an expensive transition metal catalyst. It also shows that formic acid interacts with alkynes and allyl alcohols through a carbonylation process that generates carbon monoxide in situ from nickel and palladium catalysis, respectively, doing away with the need to use high-pressure CO gas and offering a user-friendly and practical method for preparing functionalized α, β- and β, γ-unsaturated carboxylic acids. The findings presented not only enrich the field of ‘C1 chemistry,’ but also support the advancement of green and sustainable chemistry. 

Caracteristici

Nominated as an outstanding Ph.D. thesis by the University of Science and Technology of China Develops a new method for preparing ß, ?-unsaturated carboxylic acids Demonstrates that the combination of Ni(II) salt with a bisphosphine ligand and catalytic amount of acid anhydride can catalyze atom-economic hydrocarboxylation for a broad range of alkynes with formic acid